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Synthesis of cationic 2,4-dimethylpentadienylruthenium complexes. Crystal Structure of Carbonyl(η4-cyclohexa-1,3-diene)-(η5-2,4-dimethylpenta-2,4-dienyl)ruthenium Tetrafluoroborate. / Lumini, Tito
; Cox, David; Roulet, Raymond et al.
In:
Helvetica Chimica Acta, Vol. 73, No. 7, 31.10.1990, p. 1931-1934.
Research output: Contribution to Journal/Magazine › Journal article › peer-review
Harvard
Lumini, T
, Cox, D, Roulet, R, Chapuis, G & Nicolo, F 1990, '
Synthesis of cationic 2,4-dimethylpentadienylruthenium complexes. Crystal Structure of Carbonyl(η4-cyclohexa-1,3-diene)-(η5-2,4-dimethylpenta-2,4-dienyl)ruthenium Tetrafluoroborate',
Helvetica Chimica Acta, vol. 73, no. 7, pp. 1931-1934.
https://doi.org/10.1002/hlca.19900730716APA
Lumini, T.
, Cox, D., Roulet, R., Chapuis, G., & Nicolo, F. (1990).
Synthesis of cationic 2,4-dimethylpentadienylruthenium complexes. Crystal Structure of Carbonyl(η4-cyclohexa-1,3-diene)-(η5-2,4-dimethylpenta-2,4-dienyl)ruthenium Tetrafluoroborate.
Helvetica Chimica Acta,
73(7), 1931-1934.
https://doi.org/10.1002/hlca.19900730716Vancouver
Author
Bibtex
@article{f737c507918e4a59a761bbc6dc38fd96,
title = "Synthesis of cationic 2,4-dimethylpentadienylruthenium complexes.: Crystal Structure of Carbonyl(η4-cyclohexa-1,3-diene)-(η5-2,4-dimethylpenta-2,4-dienyl)ruthenium Tetrafluoroborate",
abstract = "The complex [Ru(η5-C7H11)2H]BF4 (C7H11 = 2,4-dimethylpenta-2,4-dienyl) is highly reactive towards two- and six-electron ligands. e.g. giving with CO complex [RuCO(η4-C7H12)(η5-C7H11)]BF4. The 2,4-dimethylpenta-1,3-diene ligand (C7H12) of the latter complex is readily displaced giving, e.g. with excess cyclohexa-1,3-diene (C6H8) complex [RuCO(η4-C6H8)(η5-C7H11)]BF4. These reactions provide a convenient entry into monopentadienylruthenium chemistry.",
author = "Tito Lumini and David Cox and Raymond Roulet and Gervais Chapuis and Francesco Nicolo",
year = "1990",
month = oct,
day = "31",
doi = "10.1002/hlca.19900730716",
language = "English",
volume = "73",
pages = "1931--1934",
journal = "Helvetica Chimica Acta",
issn = "1522-2675",
publisher = "Verlag Helvetica Chimica Acta AG",
number = "7",
}
RIS
TY - JOUR
T1 - Synthesis of cationic 2,4-dimethylpentadienylruthenium complexes.
T2 - Crystal Structure of Carbonyl(η4-cyclohexa-1,3-diene)-(η5-2,4-dimethylpenta-2,4-dienyl)ruthenium Tetrafluoroborate
AU - Lumini, Tito
AU - Cox, David
AU - Roulet, Raymond
AU - Chapuis, Gervais
AU - Nicolo, Francesco
PY - 1990/10/31
Y1 - 1990/10/31
N2 - The complex [Ru(η5-C7H11)2H]BF4 (C7H11 = 2,4-dimethylpenta-2,4-dienyl) is highly reactive towards two- and six-electron ligands. e.g. giving with CO complex [RuCO(η4-C7H12)(η5-C7H11)]BF4. The 2,4-dimethylpenta-1,3-diene ligand (C7H12) of the latter complex is readily displaced giving, e.g. with excess cyclohexa-1,3-diene (C6H8) complex [RuCO(η4-C6H8)(η5-C7H11)]BF4. These reactions provide a convenient entry into monopentadienylruthenium chemistry.
AB - The complex [Ru(η5-C7H11)2H]BF4 (C7H11 = 2,4-dimethylpenta-2,4-dienyl) is highly reactive towards two- and six-electron ligands. e.g. giving with CO complex [RuCO(η4-C7H12)(η5-C7H11)]BF4. The 2,4-dimethylpenta-1,3-diene ligand (C7H12) of the latter complex is readily displaced giving, e.g. with excess cyclohexa-1,3-diene (C6H8) complex [RuCO(η4-C6H8)(η5-C7H11)]BF4. These reactions provide a convenient entry into monopentadienylruthenium chemistry.
U2 - 10.1002/hlca.19900730716
DO - 10.1002/hlca.19900730716
M3 - Journal article
VL - 73
SP - 1931
EP - 1934
JO - Helvetica Chimica Acta
JF - Helvetica Chimica Acta
SN - 1522-2675
IS - 7
ER -
