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Synthesis of medium-ring and iodinated biaryl compounds by organocuprate oxidation

Research output: Contribution to journalJournal article

Published

Journal publication date11/03/2005
JournalAngewandte chemie-International edition
Journal number12
Volume44
Number of pages4
Pages1870-1873
Original languageEnglish

Abstract


A biaryl banquet! Biphenyls with four ortho substituents, heteroaromatic compounds, iodinated biaryls, and medium rings containing biaryls are all readily synthesized by organocuprate oxidation. The utility of this new methodology is illustrated by the efficient synthesis of the medium-ring core of sanguiin H-5 (see scheme).