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Synthetic control of the pore dimension and surface area in conjugated microporous polymer and copolymer networks

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Synthetic control of the pore dimension and surface area in conjugated microporous polymer and copolymer networks. / Jiang, Jia-Xing; Su, Fabing; Trewin, Abbie et al.
In: Journal of the American Chemical Society, Vol. 130, No. 24, 18.06.2008, p. 7710-7720.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Jiang, J-X, Su, F, Trewin, A, Wood, CD, Niu, H, Jones, JTA, Khimyak, YZ & Cooper, AI 2008, 'Synthetic control of the pore dimension and surface area in conjugated microporous polymer and copolymer networks', Journal of the American Chemical Society, vol. 130, no. 24, pp. 7710-7720. https://doi.org/10.1021/ja8010176

APA

Jiang, J-X., Su, F., Trewin, A., Wood, C. D., Niu, H., Jones, J. T. A., Khimyak, Y. Z., & Cooper, A. I. (2008). Synthetic control of the pore dimension and surface area in conjugated microporous polymer and copolymer networks. Journal of the American Chemical Society, 130(24), 7710-7720. https://doi.org/10.1021/ja8010176

Vancouver

Jiang J-X, Su F, Trewin A, Wood CD, Niu H, Jones JTA et al. Synthetic control of the pore dimension and surface area in conjugated microporous polymer and copolymer networks. Journal of the American Chemical Society. 2008 Jun 18;130(24):7710-7720. doi: 10.1021/ja8010176

Author

Jiang, Jia-Xing ; Su, Fabing ; Trewin, Abbie et al. / Synthetic control of the pore dimension and surface area in conjugated microporous polymer and copolymer networks. In: Journal of the American Chemical Society. 2008 ; Vol. 130, No. 24. pp. 7710-7720.

Bibtex

@article{7ef13cf104e9421c9fc53cdd0380d568,
title = "Synthetic control of the pore dimension and surface area in conjugated microporous polymer and copolymer networks",
abstract = "A series of rigid microporous poly(aryleneethynylene) (PAE) networks was synthesized by Sonogashira-Hagihara coupling chemistry. PAEs with apparent Brunauer-Emmet-Teller surface areas of more than 1000 m(2)/g were produced. The materials were found to have very good chemical and thermal stability and retention of microporosity under a variety of conditions. It was shown that physical properties such as micropore size, surface area, and hydrogen uptake could be controlled in a {"}quantized{"} fashion by varying the monomer strut length, as for metal-organic and covalent organic frameworks, even though the networks were amorphous in nature. For the first time, it was demonstrated that these properties can also be fine-tuned in a continuous manner via statistical copolymerization of monomer struts with differing lengths. This provides an unprecedented degree of direct synthetic control over micropore properties in an organic network.",
keywords = "METAL-ORGANIC FRAMEWORKS, SUPERCRITICAL CARBON-DIOXIDE, HYDROGEN STORAGE MATERIALS, OPTICAL-PROPERTIES, INTRINSIC MICROPOROSITY, COORDINATION POLYMERS, POROGENIC SOLVENT, ADSORPTION, DENDRIMERS, DESIGN",
author = "Jia-Xing Jiang and Fabing Su and Abbie Trewin and Wood, {Colin D.} and Hongjun Niu and Jones, {James T. A.} and Khimyak, {Yaroslav Z.} and Cooper, {Andrew I.}",
year = "2008",
month = jun,
day = "18",
doi = "10.1021/ja8010176",
language = "English",
volume = "130",
pages = "7710--7720",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "AMER CHEMICAL SOC",
number = "24",

}

RIS

TY - JOUR

T1 - Synthetic control of the pore dimension and surface area in conjugated microporous polymer and copolymer networks

AU - Jiang, Jia-Xing

AU - Su, Fabing

AU - Trewin, Abbie

AU - Wood, Colin D.

AU - Niu, Hongjun

AU - Jones, James T. A.

AU - Khimyak, Yaroslav Z.

AU - Cooper, Andrew I.

PY - 2008/6/18

Y1 - 2008/6/18

N2 - A series of rigid microporous poly(aryleneethynylene) (PAE) networks was synthesized by Sonogashira-Hagihara coupling chemistry. PAEs with apparent Brunauer-Emmet-Teller surface areas of more than 1000 m(2)/g were produced. The materials were found to have very good chemical and thermal stability and retention of microporosity under a variety of conditions. It was shown that physical properties such as micropore size, surface area, and hydrogen uptake could be controlled in a "quantized" fashion by varying the monomer strut length, as for metal-organic and covalent organic frameworks, even though the networks were amorphous in nature. For the first time, it was demonstrated that these properties can also be fine-tuned in a continuous manner via statistical copolymerization of monomer struts with differing lengths. This provides an unprecedented degree of direct synthetic control over micropore properties in an organic network.

AB - A series of rigid microporous poly(aryleneethynylene) (PAE) networks was synthesized by Sonogashira-Hagihara coupling chemistry. PAEs with apparent Brunauer-Emmet-Teller surface areas of more than 1000 m(2)/g were produced. The materials were found to have very good chemical and thermal stability and retention of microporosity under a variety of conditions. It was shown that physical properties such as micropore size, surface area, and hydrogen uptake could be controlled in a "quantized" fashion by varying the monomer strut length, as for metal-organic and covalent organic frameworks, even though the networks were amorphous in nature. For the first time, it was demonstrated that these properties can also be fine-tuned in a continuous manner via statistical copolymerization of monomer struts with differing lengths. This provides an unprecedented degree of direct synthetic control over micropore properties in an organic network.

KW - METAL-ORGANIC FRAMEWORKS

KW - SUPERCRITICAL CARBON-DIOXIDE

KW - HYDROGEN STORAGE MATERIALS

KW - OPTICAL-PROPERTIES

KW - INTRINSIC MICROPOROSITY

KW - COORDINATION POLYMERS

KW - POROGENIC SOLVENT

KW - ADSORPTION

KW - DENDRIMERS

KW - DESIGN

UR - http://www.scopus.com/inward/record.url?scp=45549105931&partnerID=8YFLogxK

U2 - 10.1021/ja8010176

DO - 10.1021/ja8010176

M3 - Journal article

VL - 130

SP - 7710

EP - 7720

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 24

ER -