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The determination of hydroxyl radical concentrations in environmental chambers using electron spin resonance.

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The determination of hydroxyl radical concentrations in environmental chambers using electron spin resonance. / Stokes, Neil J.; Tabner, Brian J.; Hewitt, CN.
In: Chemosphere, Vol. 28, No. 5, 1994, p. 999-1008.

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@article{c9849e6bc6a946c086caa0b5ed2ab3a0,
title = "The determination of hydroxyl radical concentrations in environmental chambers using electron spin resonance.",
abstract = "A simple sampling and analytical method for the determination of OH radical concentrations in air is described, as applied to the characterization of air in closed environmental chambers. High-volume sampling through a filter paper impregnated with α-(4-pyridyl 1-oxide)-N-tert-butylnitrone leads to the formation of an OH-spin adduct. After extraction into toluene the adduct is analysed by electron spin resonance spectroscopy. Unambiquous identification and quantification of OH radical concentrations is achieved, giving a detection limit of 5 × 104 radicals cm−3 of air and a precision of ± 25%.",
author = "Stokes, {Neil J.} and Tabner, {Brian J.} and CN Hewitt",
year = "1994",
doi = "10.1016/0045-6535(94)90016-7",
language = "English",
volume = "28",
pages = "999--1008",
journal = "Chemosphere",
publisher = "NLM (Medline)",
number = "5",

}

RIS

TY - JOUR

T1 - The determination of hydroxyl radical concentrations in environmental chambers using electron spin resonance.

AU - Stokes, Neil J.

AU - Tabner, Brian J.

AU - Hewitt, CN

PY - 1994

Y1 - 1994

N2 - A simple sampling and analytical method for the determination of OH radical concentrations in air is described, as applied to the characterization of air in closed environmental chambers. High-volume sampling through a filter paper impregnated with α-(4-pyridyl 1-oxide)-N-tert-butylnitrone leads to the formation of an OH-spin adduct. After extraction into toluene the adduct is analysed by electron spin resonance spectroscopy. Unambiquous identification and quantification of OH radical concentrations is achieved, giving a detection limit of 5 × 104 radicals cm−3 of air and a precision of ± 25%.

AB - A simple sampling and analytical method for the determination of OH radical concentrations in air is described, as applied to the characterization of air in closed environmental chambers. High-volume sampling through a filter paper impregnated with α-(4-pyridyl 1-oxide)-N-tert-butylnitrone leads to the formation of an OH-spin adduct. After extraction into toluene the adduct is analysed by electron spin resonance spectroscopy. Unambiquous identification and quantification of OH radical concentrations is achieved, giving a detection limit of 5 × 104 radicals cm−3 of air and a precision of ± 25%.

U2 - 10.1016/0045-6535(94)90016-7

DO - 10.1016/0045-6535(94)90016-7

M3 - Journal article

VL - 28

SP - 999

EP - 1008

JO - Chemosphere

JF - Chemosphere

IS - 5

ER -