Research output: Contribution to Journal/Magazine › Literature review › peer-review
Research output: Contribution to Journal/Magazine › Literature review › peer-review
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TY - JOUR
T1 - The nematic phases of bent-core liquid crystals
AU - Gleeson, Helen F.
AU - Kaur, Sarabjot
AU - Görtz, Verena
AU - Belaissaoui, Abdel
AU - Cowling, Stephen J.
AU - Goodby, John W.
PY - 2014/5/19
Y1 - 2014/5/19
N2 - Over the last ten years, the nematic phases of liquid crystals formed from bent-core structures have provoked considerable research because of their remarkable properties. This Minireview summarises some recent measurements of the physical properties of these systems, as well as describing some new data. We concentrate on oxadiazole-based materials as exemplars of this class of nematogens, but also describe some other bent-core systems. The influence of molecular structure on the stability of the nematic phase is described, together with progress in reducing the nematic transition temperatures by modifications to the molecular structure. The physical properties of bent-core nematic materials have proven difficult to study, but patterns are emerging regarding their optical and dielectric properties. Recent breakthroughs in understanding the elastic and flexoelectric behaviour are summarised. Finally, some exemplars of unusual electric field behaviour are described.
AB - Over the last ten years, the nematic phases of liquid crystals formed from bent-core structures have provoked considerable research because of their remarkable properties. This Minireview summarises some recent measurements of the physical properties of these systems, as well as describing some new data. We concentrate on oxadiazole-based materials as exemplars of this class of nematogens, but also describe some other bent-core systems. The influence of molecular structure on the stability of the nematic phase is described, together with progress in reducing the nematic transition temperatures by modifications to the molecular structure. The physical properties of bent-core nematic materials have proven difficult to study, but patterns are emerging regarding their optical and dielectric properties. Recent breakthroughs in understanding the elastic and flexoelectric behaviour are summarised. Finally, some exemplars of unusual electric field behaviour are described.
KW - bent-core molecules
KW - liquid crystals
KW - nematic phases
KW - oxadiazoles
KW - physical properties
U2 - 10.1002/cphc.201400014
DO - 10.1002/cphc.201400014
M3 - Literature review
VL - 15
SP - 1251
EP - 1260
JO - ChemPhysChem
JF - ChemPhysChem
SN - 1439-4235
IS - 7
ER -