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    Rights statement: This is the author’s version of a work that was accepted for publication in Geochimica et Cosmochimica Acta. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Geochimica et Cosmochimica Acta Volume 274, 1 April 2020, Pages 261-285 DOI: 10.1016/j.gca.2020.01.039

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Tracing interaction between hydrocarbon and groundwater systems with isotope signatures preserved in the Anyue gas field, central Sichuan Basin, China

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Tracing interaction between hydrocarbon and groundwater systems with isotope signatures preserved in the Anyue gas field, central Sichuan Basin, China. / Li, Yan; Qin, Shengfei; Wang, Yunpeng; Holland, Greg; Zhou, Zheng.

In: Geochimica et Cosmochimica Acta, Vol. 274, 01.04.2020, p. 261-285.

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@article{3c3635f327744498a2f387937fb54cc3,
title = "Tracing interaction between hydrocarbon and groundwater systems with isotope signatures preserved in the Anyue gas field, central Sichuan Basin, China",
abstract = "Anyue gas field is a large gas field located in the central Sichuan Basin, China. Although many studies have been carried out previously, the formation mechanism of this field is unclear and currently under debate. To better understand the accumulation history, the role that groundwater plays in transporting hydrocarbons within sedimentary basins and water-gas interactions, stable and noble gas isotopes were measured in thirteen free gas samples from the Anyue gas field. In addition, nine formation water samples and five reservoir bitumen samples were analyzed for stable carbon isotopes. δ13C(CH4) values in the gas samples range from −35.0 to −32.6‰, showing evidence of thermogenic origin. δ13C values among three different types of samples (free gases, water-dissolved gases and reservoir bitumen) show a pattern that cannot be explained by oil cracking followed by free gas accumulation. It suggests the occurrence of gas-groundwater interaction in the Anyue field. Free gas samples can be divided into 2 distinct groups by their geographical locations and stratigraphical source formations. 3He/4He ratios (R/Ra) in group 1 and group 2 samples range from 0.0118 to 0.0132 and 0.0115 to 0.0256, respectively, indicating He is mainly derived from the crust. 20Ne/22Ne and 21Ne/22Ne ratios suggest a mixing between the air and crust sources. 40Ar/36Ar ratios ranging from 1658 to 2109 and 2168 to 5973 in group 1 and group 2 samples, respectively, are significantly higher than the air value of 298.6. In comparison, heavier noble gas (Kr and Xe) isotopic compositions are predominantly air-like. The relative enrichment of 4He and 21Ne* in group 1 samples can be possibly explained by preferential release of light noble gases in a low temperature environment. Samples in group 2 show a good fit to the solubility-controlled Rayleigh fractionation model, suggesting the presence of an open system degassing of gases from the groundwater. The excess heavy noble gases in natural gas samples can be attributed to the addition of sedimentary components from the source rocks during geological evolution. 4He groundwater ages considering in-situ production and external flux indicate the addition of young groundwater into the Anyue gas field. Low gas-groundwater ratios and high CH4/36Ar ratios suggest that only a small portion of the gases in the current Longwangmiao reservoir of Anyue gas field has been in contact with the relatively young groundwater. Based on the noble gas and stable carbon isotope results in all samples, we propose a two-stage gas and groundwater interaction process during the gas preservation and accumulation history in the Anyue gas field in China.",
keywords = "Gas groundwater interaction, Gas-water ratio, Groundwater age, Hydrocarbon gases, Noble gases",
author = "Yan Li and Shengfei Qin and Yunpeng Wang and Greg Holland and Zheng Zhou",
note = "This is the author{\textquoteright}s version of a work that was accepted for publication in Geochimica et Cosmochimica Acta. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Geochimica et Cosmochimica Acta Volume 274, 1 April 2020, Pages 261-285 DOI: 10.1016/j.gca.2020.01.039 ",
year = "2020",
month = apr
day = "1",
doi = "10.1016/j.gca.2020.01.039",
language = "English",
volume = "274",
pages = "261--285",
journal = "Geochimica et Cosmochimica Acta",
issn = "0016-7037",
publisher = "Elsevier Limited",

}

RIS

TY - JOUR

T1 - Tracing interaction between hydrocarbon and groundwater systems with isotope signatures preserved in the Anyue gas field, central Sichuan Basin, China

AU - Li, Yan

AU - Qin, Shengfei

AU - Wang, Yunpeng

AU - Holland, Greg

AU - Zhou, Zheng

N1 - This is the author’s version of a work that was accepted for publication in Geochimica et Cosmochimica Acta. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Geochimica et Cosmochimica Acta Volume 274, 1 April 2020, Pages 261-285 DOI: 10.1016/j.gca.2020.01.039

PY - 2020/4/1

Y1 - 2020/4/1

N2 - Anyue gas field is a large gas field located in the central Sichuan Basin, China. Although many studies have been carried out previously, the formation mechanism of this field is unclear and currently under debate. To better understand the accumulation history, the role that groundwater plays in transporting hydrocarbons within sedimentary basins and water-gas interactions, stable and noble gas isotopes were measured in thirteen free gas samples from the Anyue gas field. In addition, nine formation water samples and five reservoir bitumen samples were analyzed for stable carbon isotopes. δ13C(CH4) values in the gas samples range from −35.0 to −32.6‰, showing evidence of thermogenic origin. δ13C values among three different types of samples (free gases, water-dissolved gases and reservoir bitumen) show a pattern that cannot be explained by oil cracking followed by free gas accumulation. It suggests the occurrence of gas-groundwater interaction in the Anyue field. Free gas samples can be divided into 2 distinct groups by their geographical locations and stratigraphical source formations. 3He/4He ratios (R/Ra) in group 1 and group 2 samples range from 0.0118 to 0.0132 and 0.0115 to 0.0256, respectively, indicating He is mainly derived from the crust. 20Ne/22Ne and 21Ne/22Ne ratios suggest a mixing between the air and crust sources. 40Ar/36Ar ratios ranging from 1658 to 2109 and 2168 to 5973 in group 1 and group 2 samples, respectively, are significantly higher than the air value of 298.6. In comparison, heavier noble gas (Kr and Xe) isotopic compositions are predominantly air-like. The relative enrichment of 4He and 21Ne* in group 1 samples can be possibly explained by preferential release of light noble gases in a low temperature environment. Samples in group 2 show a good fit to the solubility-controlled Rayleigh fractionation model, suggesting the presence of an open system degassing of gases from the groundwater. The excess heavy noble gases in natural gas samples can be attributed to the addition of sedimentary components from the source rocks during geological evolution. 4He groundwater ages considering in-situ production and external flux indicate the addition of young groundwater into the Anyue gas field. Low gas-groundwater ratios and high CH4/36Ar ratios suggest that only a small portion of the gases in the current Longwangmiao reservoir of Anyue gas field has been in contact with the relatively young groundwater. Based on the noble gas and stable carbon isotope results in all samples, we propose a two-stage gas and groundwater interaction process during the gas preservation and accumulation history in the Anyue gas field in China.

AB - Anyue gas field is a large gas field located in the central Sichuan Basin, China. Although many studies have been carried out previously, the formation mechanism of this field is unclear and currently under debate. To better understand the accumulation history, the role that groundwater plays in transporting hydrocarbons within sedimentary basins and water-gas interactions, stable and noble gas isotopes were measured in thirteen free gas samples from the Anyue gas field. In addition, nine formation water samples and five reservoir bitumen samples were analyzed for stable carbon isotopes. δ13C(CH4) values in the gas samples range from −35.0 to −32.6‰, showing evidence of thermogenic origin. δ13C values among three different types of samples (free gases, water-dissolved gases and reservoir bitumen) show a pattern that cannot be explained by oil cracking followed by free gas accumulation. It suggests the occurrence of gas-groundwater interaction in the Anyue field. Free gas samples can be divided into 2 distinct groups by their geographical locations and stratigraphical source formations. 3He/4He ratios (R/Ra) in group 1 and group 2 samples range from 0.0118 to 0.0132 and 0.0115 to 0.0256, respectively, indicating He is mainly derived from the crust. 20Ne/22Ne and 21Ne/22Ne ratios suggest a mixing between the air and crust sources. 40Ar/36Ar ratios ranging from 1658 to 2109 and 2168 to 5973 in group 1 and group 2 samples, respectively, are significantly higher than the air value of 298.6. In comparison, heavier noble gas (Kr and Xe) isotopic compositions are predominantly air-like. The relative enrichment of 4He and 21Ne* in group 1 samples can be possibly explained by preferential release of light noble gases in a low temperature environment. Samples in group 2 show a good fit to the solubility-controlled Rayleigh fractionation model, suggesting the presence of an open system degassing of gases from the groundwater. The excess heavy noble gases in natural gas samples can be attributed to the addition of sedimentary components from the source rocks during geological evolution. 4He groundwater ages considering in-situ production and external flux indicate the addition of young groundwater into the Anyue gas field. Low gas-groundwater ratios and high CH4/36Ar ratios suggest that only a small portion of the gases in the current Longwangmiao reservoir of Anyue gas field has been in contact with the relatively young groundwater. Based on the noble gas and stable carbon isotope results in all samples, we propose a two-stage gas and groundwater interaction process during the gas preservation and accumulation history in the Anyue gas field in China.

KW - Gas groundwater interaction

KW - Gas-water ratio

KW - Groundwater age

KW - Hydrocarbon gases

KW - Noble gases

U2 - 10.1016/j.gca.2020.01.039

DO - 10.1016/j.gca.2020.01.039

M3 - Journal article

AN - SCOPUS:85079663819

VL - 274

SP - 261

EP - 285

JO - Geochimica et Cosmochimica Acta

JF - Geochimica et Cosmochimica Acta

SN - 0016-7037

ER -