Final published version
Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Tracking the fingerprints and combined TOC–black carbon mediated soil–air partitioning of polychlorinated naphthalenes (PCNs) in the Indus River Basin of Pakistan
AU - Ali, Usman
AU - Sánchez-García, Laura
AU - Rehman, Muhammad Yasir Abdur
AU - Syed, Jabir Hussain
AU - Mahmood, Adeel
AU - Li, Jun
AU - Zhang, Gan
AU - Jones, Kevin Christopher
AU - Malik, Riffat Naseem
PY - 2016/1
Y1 - 2016/1
N2 - This study reports the first investigation of polychlorinated naphthalenes (PCNs) in air and soil samples from ecologically important sites of the Indus River Basin, Pakistan. The concentrations of ∑39-PCNs in air and soil were found in a range between 1–1588 pg m−3 and 0.02–23 ng g−1 while the mean TEQ values were calculated to be 5.4E−04 pg TEQ m−3 and 1.6E+01 pg TEQ g−1, respectively. Spatially, air and soil PCN concentrations were found to be high at Rahim Yar Khan (agricultural region). Lower-medium chlorinated PCNs (sum of tri-, tetra- and penta-CNs) predominated in both air and soil, altogether constituting 87 and 86% of total PCNs in the two environmental matrices, respectively. According to the data, soil–air partitioning of PCNs was interpreted to be similarly controlled by the combined effect of black carbon and organic matter in the Indus River Basin, with no preferential implication of the recalcitrant organic form.
AB - This study reports the first investigation of polychlorinated naphthalenes (PCNs) in air and soil samples from ecologically important sites of the Indus River Basin, Pakistan. The concentrations of ∑39-PCNs in air and soil were found in a range between 1–1588 pg m−3 and 0.02–23 ng g−1 while the mean TEQ values were calculated to be 5.4E−04 pg TEQ m−3 and 1.6E+01 pg TEQ g−1, respectively. Spatially, air and soil PCN concentrations were found to be high at Rahim Yar Khan (agricultural region). Lower-medium chlorinated PCNs (sum of tri-, tetra- and penta-CNs) predominated in both air and soil, altogether constituting 87 and 86% of total PCNs in the two environmental matrices, respectively. According to the data, soil–air partitioning of PCNs was interpreted to be similarly controlled by the combined effect of black carbon and organic matter in the Indus River Basin, with no preferential implication of the recalcitrant organic form.
KW - PCNs
KW - Soil–air partition model
KW - Sorption
KW - Octanol–air partition coefficient
KW - Black carbon–air partition coefficient
U2 - 10.1016/j.envpol.2015.10.005
DO - 10.1016/j.envpol.2015.10.005
M3 - Journal article
VL - 208
SP - 850
EP - 858
JO - Environmental Pollution
JF - Environmental Pollution
SN - 0269-7491
IS - Part B
ER -