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Transformative 3d-4f coordination cluster carriers

Research output: Contribution to journalJournal articlepeer-review

Published
<mark>Journal publication date</mark>21/09/2018
<mark>Journal</mark>Dalton Transactions
Issue number35
Volume47
Number of pages24
Pages (from-to)12011-12034
Publication StatusPublished
<mark>Original language</mark>English

Abstract

The aim of this perspective is to summarise the use of the reported 3d-4f Coordination Clusters (CCs) in catalytic reactions and to demonstrate the potential of this emerging field. The pioneering work of Shibasaki, Matsunaga and others, demonstrated the use of 3d-4f in situ systems to catalyse asymmetric organic transformations. Our recent studies show that well characterised 3d-4f CCs catalyse numerous organic transformations and useful mechanistic aspects of their catalysis can be obtained. Furthermore, we have shown that by manipulation of the metal ion coordination environment; the nature of the 3d and lanthanide ions and the organic periphery of the ligand can all improve the efficacy of a 3d-4f CC catalyst. All in situ formed and well characterized 3d-4f CCs involved in catalysis are discussed.