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Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - White phosphorus activation by a Th(III) complex
AU - Formanuik, Alasdair
AU - Ortu, Fabrizio
AU - Beekmeyer, Reece
AU - Kerridge, Andrew
AU - Adams, Ralph
AU - Mills, David
PY - 2016/2/14
Y1 - 2016/2/14
N2 - [Th(Cp′′)3] (Cp′′ = {C5H3(SiMe3)2-1,3}) activates P4 to give [{Th(Cp′′)3}2(μ–η1:η1-P4)] (1), which has an unprecedented cyclo-P4 binding mode. DFT studies were performed on a model of 1 to probe the bonding in this system.
AB - [Th(Cp′′)3] (Cp′′ = {C5H3(SiMe3)2-1,3}) activates P4 to give [{Th(Cp′′)3}2(μ–η1:η1-P4)] (1), which has an unprecedented cyclo-P4 binding mode. DFT studies were performed on a model of 1 to probe the bonding in this system.
U2 - 10.1039/C5DT04528B
DO - 10.1039/C5DT04528B
M3 - Journal article
VL - 45
SP - 2390
EP - 2393
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9226
IS - 6
ER -