Research output: Contribution to Journal/Magazine › Journal article › peer-review
| <mark>Journal publication date</mark> | 2012 |
|---|---|
| <mark>Journal</mark> | Dalton Transactions |
| Issue number | 14 |
| Volume | 41 |
| Number of pages | 5 |
| Pages (from-to) | 3937-3941 |
| Publication Status | Published |
| <mark>Original language</mark> | English |
The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO2 adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO2.