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A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO2 adsorption

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO2 adsorption. / Mowat, John P. S.; Seymour, Valerie R.; Griffin, John M. et al.

In: Dalton Transactions, Vol. 41, No. 14, 2012, p. 3937-3941.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Mowat, JPS, Seymour, VR, Griffin, JM, Thompson, SP, Slawin, AMZ, Fairen-Jimenez, D, Dueren, T, Ashbrook, SE & Wright, PA 2012, 'A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO2 adsorption', Dalton Transactions, vol. 41, no. 14, pp. 3937-3941. https://doi.org/10.1039/c1dt11729g

APA

Mowat, J. P. S., Seymour, V. R., Griffin, J. M., Thompson, S. P., Slawin, A. M. Z., Fairen-Jimenez, D., Dueren, T., Ashbrook, S. E., & Wright, P. A. (2012). A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO2 adsorption. Dalton Transactions, 41(14), 3937-3941. https://doi.org/10.1039/c1dt11729g

Vancouver

Mowat JPS, Seymour VR, Griffin JM, Thompson SP, Slawin AMZ, Fairen-Jimenez D et al. A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO2 adsorption. Dalton Transactions. 2012;41(14):3937-3941. doi: 10.1039/c1dt11729g

Author

Mowat, John P. S. ; Seymour, Valerie R. ; Griffin, John M. et al. / A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO2 adsorption. In: Dalton Transactions. 2012 ; Vol. 41, No. 14. pp. 3937-3941.

Bibtex

@article{d676ce917ee24291a47fe9d3f20ad798,
title = "A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO2 adsorption",
abstract = "The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO2 adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO2.",
keywords = "METAL-ORGANIC FRAMEWORKS, QUANTUM MAS NMR, BENZENEDICARBOXYLATE, TEREPHTHALATE, MIL-47(V)",
author = "Mowat, {John P. S.} and Seymour, {Valerie R.} and Griffin, {John M.} and Thompson, {Stephen P.} and Slawin, {Alexandra M. Z.} and David Fairen-Jimenez and Tina Dueren and Ashbrook, {Sharon E.} and Wright, {Paul A.}",
year = "2012",
doi = "10.1039/c1dt11729g",
language = "English",
volume = "41",
pages = "3937--3941",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "14",

}

RIS

TY - JOUR

T1 - A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO2 adsorption

AU - Mowat, John P. S.

AU - Seymour, Valerie R.

AU - Griffin, John M.

AU - Thompson, Stephen P.

AU - Slawin, Alexandra M. Z.

AU - Fairen-Jimenez, David

AU - Dueren, Tina

AU - Ashbrook, Sharon E.

AU - Wright, Paul A.

PY - 2012

Y1 - 2012

N2 - The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO2 adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO2.

AB - The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO2 adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO2.

KW - METAL-ORGANIC FRAMEWORKS

KW - QUANTUM MAS NMR

KW - BENZENEDICARBOXYLATE

KW - TEREPHTHALATE

KW - MIL-47(V)

U2 - 10.1039/c1dt11729g

DO - 10.1039/c1dt11729g

M3 - Journal article

VL - 41

SP - 3937

EP - 3941

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 14

ER -