Research output: Contribution to Journal/Magazine › Journal article › peer-review
A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO2 adsorption. / Mowat, John P. S.; Seymour, Valerie R.; Griffin, John M. et al.
In: Dalton Transactions, Vol. 41, No. 14, 2012, p. 3937-3941.Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO2 adsorption
AU - Mowat, John P. S.
AU - Seymour, Valerie R.
AU - Griffin, John M.
AU - Thompson, Stephen P.
AU - Slawin, Alexandra M. Z.
AU - Fairen-Jimenez, David
AU - Dueren, Tina
AU - Ashbrook, Sharon E.
AU - Wright, Paul A.
PY - 2012
Y1 - 2012
N2 - The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO2 adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO2.
AB - The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO2 adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO2.
KW - METAL-ORGANIC FRAMEWORKS
KW - QUANTUM MAS NMR
KW - BENZENEDICARBOXYLATE
KW - TEREPHTHALATE
KW - MIL-47(V)
U2 - 10.1039/c1dt11729g
DO - 10.1039/c1dt11729g
M3 - Journal article
VL - 41
SP - 3937
EP - 3941
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9226
IS - 14
ER -