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Home > Research > Publications & Outputs > Catalytic decarboxylative alkenylation of enolates
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Catalytic decarboxylative alkenylation of enolates

Research output: Contribution to journalLetter

Published

Journal publication date19/07/2013
JournalOrganic letters
Journal number14
Volume15
Number of pages4
Pages3778-3781
Original languageEnglish

Abstract

A palladium-catalyzed decarboxylative alkenylation of stabilized enolates has been developed, which gives rise to alkenylated dicarbonyl products from enol carbonates regioselectively with concomitant installation of a quaternary all-carbon center. The broad scope of the reaction has been demonstrated by successfully utilizing a range of enolates and external phenol nucleophiles.