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Home > Research > Publications & Outputs > Catalytic decarboxylative alkenylation of enolates
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Catalytic decarboxylative alkenylation of enolates

Research output: Contribution to journalJournal article

Published

<mark>Journal publication date</mark>19/07/2013
<mark>Journal</mark>Organic Letters
Issue14
Volume15
Number of pages4
Pages3778-3781
<mark>Original language</mark>English

Abstract

A palladium-catalyzed decarboxylative alkenylation of stabilized enolates has been developed, which gives rise to alkenylated dicarbonyl products from enol carbonates regioselectively with concomitant installation of a quaternary all-carbon center. The broad scope of the reaction has been demonstrated by successfully utilizing a range of enolates and external phenol nucleophiles.