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Catalytic decarboxylative alkenylation of enolates

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Catalytic decarboxylative alkenylation of enolates. / Schroeder, Sybrin; Taylor, Nicholas; Jackson, Paula et al.
In: Organic Letters, Vol. 15, No. 14, 19.07.2013, p. 3778-3781.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Schroeder, S, Taylor, N, Jackson, P & Franckevicius, V 2013, 'Catalytic decarboxylative alkenylation of enolates', Organic Letters, vol. 15, no. 14, pp. 3778-3781. https://doi.org/10.1021/ol401729m

APA

Schroeder, S., Taylor, N., Jackson, P., & Franckevicius, V. (2013). Catalytic decarboxylative alkenylation of enolates. Organic Letters, 15(14), 3778-3781. https://doi.org/10.1021/ol401729m

Vancouver

Schroeder S, Taylor N, Jackson P, Franckevicius V. Catalytic decarboxylative alkenylation of enolates. Organic Letters. 2013 Jul 19;15(14):3778-3781. doi: 10.1021/ol401729m

Author

Schroeder, Sybrin ; Taylor, Nicholas ; Jackson, Paula et al. / Catalytic decarboxylative alkenylation of enolates. In: Organic Letters. 2013 ; Vol. 15, No. 14. pp. 3778-3781.

Bibtex

@article{9a6e8dcda67549e49c4d263b15c254de,
title = "Catalytic decarboxylative alkenylation of enolates",
abstract = "A palladium-catalyzed decarboxylative alkenylation of stabilized enolates has been developed, which gives rise to alkenylated dicarbonyl products from enol carbonates regioselectively with concomitant installation of a quaternary all-carbon center. The broad scope of the reaction has been demonstrated by successfully utilizing a range of enolates and external phenol nucleophiles.",
keywords = "Decarboxylation, Alkenylation, Enolates, Propargylic compounds, phenols",
author = "Sybrin Schroeder and Nicholas Taylor and Paula Jackson and Vilius Franckevicius",
year = "2013",
month = jul,
day = "19",
doi = "10.1021/ol401729m",
language = "English",
volume = "15",
pages = "3778--3781",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "14",

}

RIS

TY - JOUR

T1 - Catalytic decarboxylative alkenylation of enolates

AU - Schroeder, Sybrin

AU - Taylor, Nicholas

AU - Jackson, Paula

AU - Franckevicius, Vilius

PY - 2013/7/19

Y1 - 2013/7/19

N2 - A palladium-catalyzed decarboxylative alkenylation of stabilized enolates has been developed, which gives rise to alkenylated dicarbonyl products from enol carbonates regioselectively with concomitant installation of a quaternary all-carbon center. The broad scope of the reaction has been demonstrated by successfully utilizing a range of enolates and external phenol nucleophiles.

AB - A palladium-catalyzed decarboxylative alkenylation of stabilized enolates has been developed, which gives rise to alkenylated dicarbonyl products from enol carbonates regioselectively with concomitant installation of a quaternary all-carbon center. The broad scope of the reaction has been demonstrated by successfully utilizing a range of enolates and external phenol nucleophiles.

KW - Decarboxylation

KW - Alkenylation

KW - Enolates

KW - Propargylic compounds

KW - phenols

U2 - 10.1021/ol401729m

DO - 10.1021/ol401729m

M3 - Journal article

AN - SCOPUS:84880519231

VL - 15

SP - 3778

EP - 3781

JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 14

ER -