Atmospheric concentrations are reported for the main component of the brominated flame retardant decaBDE (BDE-209) in air samples collected from Southern Ontario for the period January 23–June 06, 2002. Levels ranged from below detection to 105 pg m−3 with virtually all of BDE-209 being trapped by the filter and thus deduced to be sorbed to aerosol particles. Thus, it is likely that the long-range atmospheric transport (LRAT) of BDE-209 is controlled by the transport characteristics of the aerosols. This conclusion that BDE-209 does not have the same potential for LRAT as other more volatile PBDEs is subject to possible complications arising from the uncertainties about the LRAT potential of aerosols.