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Conjugated microporous poly (aryleneethynylene) networks

Research output: Contribution to journalJournal article

Published

  • Jia-Xing Jiang
  • Fabing Su
  • Abbie Trewin
  • Colin D. Wood
  • Nell L. Campbell
  • Hongjun Niu
  • Calum Dickinson
  • Alexey Y. Ganin
  • Matthew J. Rosseinsky
  • Yaroslav Z. Khimyak
  • Andrew I. Cooper
Journal publication date19/11/2007
JournalAngewandte Chemie International Edition
Journal number45
Volume46
Number of pages5
Pages8574-8578
Original languageEnglish

Abstract

Rigid wiry nets: Conjugated microporous polymer networks are formed by Sonogashira–Hagihara coupling. Although these materials are amorphous, the micropore size and surface area can be controlled by varying the length of the phenyleneethynylene struts (see picture; the network is shown in blue, and one 1,3,5-substituted benzene node and three connected struts are highlighted with C gray and H white).

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