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Conjugated microporous poly (aryleneethynylene) networks

Research output: Contribution to Journal/MagazineJournal articlepeer-review

  • Jia-Xing Jiang
  • Fabing Su
  • Abbie Trewin
  • Colin D. Wood
  • Nell L. Campbell
  • Hongjun Niu
  • Calum Dickinson
  • Alexey Y. Ganin
  • Matthew J. Rosseinsky
  • Yaroslav Z. Khimyak
  • Andrew I. Cooper
<mark>Journal publication date</mark>19/11/2007
<mark>Journal</mark>Angewandte Chemie International Edition
Issue number45
Number of pages5
Pages (from-to)8574-8578
Publication StatusPublished
<mark>Original language</mark>English


Rigid wiry nets: Conjugated microporous polymer networks are formed by Sonogashira–Hagihara coupling. Although these materials are amorphous, the micropore size and surface area can be controlled by varying the length of the phenyleneethynylene struts (see picture; the network is shown in blue, and one 1,3,5-substituted benzene node and three connected struts are highlighted with C gray and H white).