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Effects of Electrode-Molecule Binding and Junction Geometry on the Single-Molecule Conductance of bis-2,2′:6′,2″-Terpyridine-based Complexes

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Effects of Electrode-Molecule Binding and Junction Geometry on the Single-Molecule Conductance of bis-2,2′:6′,2″-Terpyridine-based Complexes. / Davidson, Ross; Al-Owaedi, Oday; Milan, David C. et al.
In: Inorganic Chemistry, Vol. 55, No. 6, 21.03.2016, p. 2691-2700.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Davidson, R, Al-Owaedi, O, Milan, DC, Zeng, Q, Tory, J, Hartl, F, Higgins, SJ, Nichols, RJ, Lambert, CJ & Low, PJ 2016, 'Effects of Electrode-Molecule Binding and Junction Geometry on the Single-Molecule Conductance of bis-2,2′:6′,2″-Terpyridine-based Complexes', Inorganic Chemistry, vol. 55, no. 6, pp. 2691-2700. https://doi.org/10.1021/acs.inorgchem.5b02094

APA

Davidson, R., Al-Owaedi, O., Milan, D. C., Zeng, Q., Tory, J., Hartl, F., Higgins, S. J., Nichols, R. J., Lambert, C. J., & Low, P. J. (2016). Effects of Electrode-Molecule Binding and Junction Geometry on the Single-Molecule Conductance of bis-2,2′:6′,2″-Terpyridine-based Complexes. Inorganic Chemistry, 55(6), 2691-2700. https://doi.org/10.1021/acs.inorgchem.5b02094

Vancouver

Davidson R, Al-Owaedi O, Milan DC, Zeng Q, Tory J, Hartl F et al. Effects of Electrode-Molecule Binding and Junction Geometry on the Single-Molecule Conductance of bis-2,2′:6′,2″-Terpyridine-based Complexes. Inorganic Chemistry. 2016 Mar 21;55(6):2691-2700. Epub 2016 Feb 24. doi: 10.1021/acs.inorgchem.5b02094

Author

Davidson, Ross ; Al-Owaedi, Oday ; Milan, David C. et al. / Effects of Electrode-Molecule Binding and Junction Geometry on the Single-Molecule Conductance of bis-2,2′:6′,2″-Terpyridine-based Complexes. In: Inorganic Chemistry. 2016 ; Vol. 55, No. 6. pp. 2691-2700.

Bibtex

@article{dc56cb650fd243eca8a7c4d5dc5d4d24,
title = "Effects of Electrode-Molecule Binding and Junction Geometry on the Single-Molecule Conductance of bis-2,2′:6′,2″-Terpyridine-based Complexes",
abstract = "The single molecule conductances of a series of bis-2,2′:6′,2″-terpyridine complexes featuring Ru(II), Fe(II), and Co(II) metal ions and trimethylsilylethynyl (Me3SiC≡C-) or thiomethyl (MeS-) surface contact groups have been determined. In the absence of electrochemical gating, these complexes behave as tunneling barriers, with conductance properties determined more by the strength of the electrode-molecule contact and the structure of the {"}linker{"} than the nature of the metal-ion or redox properties of the complex.",
author = "Ross Davidson and Oday Al-Owaedi and Milan, {David C.} and Qiang Zeng and Joanne Tory and Frantisek Hartl and Higgins, {Simon J.} and Nichols, {Richard J.} and Lambert, {Colin John} and Low, {Paul J.}",
year = "2016",
month = mar,
day = "21",
doi = "10.1021/acs.inorgchem.5b02094",
language = "English",
volume = "55",
pages = "2691--2700",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "6",

}

RIS

TY - JOUR

T1 - Effects of Electrode-Molecule Binding and Junction Geometry on the Single-Molecule Conductance of bis-2,2′:6′,2″-Terpyridine-based Complexes

AU - Davidson, Ross

AU - Al-Owaedi, Oday

AU - Milan, David C.

AU - Zeng, Qiang

AU - Tory, Joanne

AU - Hartl, Frantisek

AU - Higgins, Simon J.

AU - Nichols, Richard J.

AU - Lambert, Colin John

AU - Low, Paul J.

PY - 2016/3/21

Y1 - 2016/3/21

N2 - The single molecule conductances of a series of bis-2,2′:6′,2″-terpyridine complexes featuring Ru(II), Fe(II), and Co(II) metal ions and trimethylsilylethynyl (Me3SiC≡C-) or thiomethyl (MeS-) surface contact groups have been determined. In the absence of electrochemical gating, these complexes behave as tunneling barriers, with conductance properties determined more by the strength of the electrode-molecule contact and the structure of the "linker" than the nature of the metal-ion or redox properties of the complex.

AB - The single molecule conductances of a series of bis-2,2′:6′,2″-terpyridine complexes featuring Ru(II), Fe(II), and Co(II) metal ions and trimethylsilylethynyl (Me3SiC≡C-) or thiomethyl (MeS-) surface contact groups have been determined. In the absence of electrochemical gating, these complexes behave as tunneling barriers, with conductance properties determined more by the strength of the electrode-molecule contact and the structure of the "linker" than the nature of the metal-ion or redox properties of the complex.

U2 - 10.1021/acs.inorgchem.5b02094

DO - 10.1021/acs.inorgchem.5b02094

M3 - Journal article

VL - 55

SP - 2691

EP - 2700

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 6

ER -