Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Giant thermopower and figure of merit in single-molecule devices
AU - Finch, C. M.
AU - Garcia-Suarez, V. M.
AU - Lambert, Colin
PY - 2009/1
Y1 - 2009/1
N2 - We present a study of the thermopower S and the dimensionless figure of merit ZT in molecules sandwiched between gold electrodes. We show that for molecules with side groups, the shape of the transmission coefficient can be dramatically modified by Fano resonances near the Fermi energy, which can be tuned to produce huge increases in S and ZT. This shows that molecules exhibiting Fano resonances have a high efficiency of thermoelectric cooling which is not present for conventional ungated molecules with only delocalized states along their backbone.
AB - We present a study of the thermopower S and the dimensionless figure of merit ZT in molecules sandwiched between gold electrodes. We show that for molecules with side groups, the shape of the transmission coefficient can be dramatically modified by Fano resonances near the Fermi energy, which can be tuned to produce huge increases in S and ZT. This shows that molecules exhibiting Fano resonances have a high efficiency of thermoelectric cooling which is not present for conventional ungated molecules with only delocalized states along their backbone.
UR - http://www.scopus.com/inward/record.url?scp=59249090719&partnerID=8YFLogxK
U2 - 10.1103/PhysRevB.79.033405
DO - 10.1103/PhysRevB.79.033405
M3 - Journal article
VL - 79
SP - -
JO - Physical review B
JF - Physical review B
SN - 1098-0121
IS - 3
M1 - 033405
ER -