Home > Research > Publications & Outputs > Oscillating Seebeck coefficients in π-stacked m...

Associated organisational unit

Links

Text available via DOI:

View graph of relations

Oscillating Seebeck coefficients in π-stacked molecular junctions

Research output: Contribution to journalJournal article

Published
<mark>Journal publication date</mark>10/07/2018
<mark>Journal</mark>RSC Advances
Issue number44
Volume8
Number of pages5
Pages (from-to)24711-24715
Publication statusPublished
Original languageEnglish

Abstract

When a linear aromatic molecule within a nanogap is bound only to a source electrode, and an adjacent molecule is bound only to a drain electrode, the two molecules can interact via pi-pi stacking, which allows electrons to flow from the source to the drain, via pi-pi bonds. Here we investigate the thermoelectric properties of such junctions, using mono-thiol oligo-phenylene ethynylene (OPE3)-based molecules as a model system. For molecules which are para-connected to the electrodes, we show that the Seebeck coefficient is an oscillatory function of the length L of the pi-pi overlap region and exhibits large positive and negative values. This bi-thermoelectric behavior is a result of quantum interference within the junction, which behaves like a molecular-scale Mach-Zehnder interferometer. For junctions formed from molecular monolayers sandwiched between planar electrodes, this allows both hole-like and electron-like Seebeck coefficients to be realized, by careful control of electrode separation On the other hand for meta-connected molecules, the Seebeck coefficient is insensitive to L, which may be helpful in designing resilient junctions with more stable and predictable thermoelectric properties.