This dataset contains discharge and surface water chemistry for the six river reaches of contrasting geology (clay, sand, chalk) in the Hampshire Avon. Manual measurements of discharge by the velocity-area method enabled construction of a stage-discharge relationship for each site. Stream stage was measured using pressure transducers from Summer 2013 to Summer 2015. River water samples were collected at 48-hr intervals from Summer 2013 to Summer 2014 and samples were analysed for selected solutes and suspended sediment.