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(33)S MAS NMR of a disordered sulfur-doped silicate: signal enhancement via RAPT, QCPMG and adiabatic pulses

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(33)S MAS NMR of a disordered sulfur-doped silicate: signal enhancement via RAPT, QCPMG and adiabatic pulses. / O'Dell, L. A.; Klimm, K.; Freitas, J. C. C. et al.
In: Applied Magnetic Resonance, Vol. 35, No. 2, 01.02.2009, p. 247-259.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

O'Dell, LA, Klimm, K, Freitas, JCC, Kohn, SC & Smith, ME 2009, '(33)S MAS NMR of a disordered sulfur-doped silicate: signal enhancement via RAPT, QCPMG and adiabatic pulses', Applied Magnetic Resonance, vol. 35, no. 2, pp. 247-259. https://doi.org/10.1007/s00723-008-0159-8

APA

O'Dell, L. A., Klimm, K., Freitas, J. C. C., Kohn, S. C., & Smith, M. E. (2009). (33)S MAS NMR of a disordered sulfur-doped silicate: signal enhancement via RAPT, QCPMG and adiabatic pulses. Applied Magnetic Resonance, 35(2), 247-259. https://doi.org/10.1007/s00723-008-0159-8

Vancouver

O'Dell LA, Klimm K, Freitas JCC, Kohn SC, Smith ME. (33)S MAS NMR of a disordered sulfur-doped silicate: signal enhancement via RAPT, QCPMG and adiabatic pulses. Applied Magnetic Resonance. 2009 Feb 1;35(2):247-259. doi: 10.1007/s00723-008-0159-8

Author

O'Dell, L. A. ; Klimm, K. ; Freitas, J. C. C. et al. / (33)S MAS NMR of a disordered sulfur-doped silicate: signal enhancement via RAPT, QCPMG and adiabatic pulses. In: Applied Magnetic Resonance. 2009 ; Vol. 35, No. 2. pp. 247-259.

Bibtex

@article{1cfeae189e3b440d962f11a6c75bbf3e,
title = "(33)S MAS NMR of a disordered sulfur-doped silicate: signal enhancement via RAPT, QCPMG and adiabatic pulses",
abstract = "Three different signal enhancement techniques have been applied to (33)S magic-angle spinning nuclear magnetic resonance (MAS NMR) of a disordered silicate containing 1.15 wt% (33)S. Partial saturation of the satellite transitions was achieved using a rotor-assisted population transfer (RAPT) pulse sequence, resulting in a signal enhancement of 1.63, albeit with a slight distortion of the line shape due to selective excitation. Adiabatic inversion of the satellite transitions by various amplitude-and frequency-modulated pulse shapes (such as hyperbolic secant and wideband uniform-rate smooth truncation) was also attempted, resulting in a signal enhancement of up to 1.85, with no apparent line shape distortion. Quadrupolar Carr-Purcell-Meiboom-Gill (QCPMG) and RAPT-QCPMG sequences were also used, both of which yielded spikelet spectra that accurately reflected the MAS line shape with a greatly improved signal-to-noise ratio. It is hoped that this study demonstrates that (33)S solid-state MAS NMR is now feasible even on disordered, low-sulfur-content systems.",
keywords = "INTEGER QUADRUPOLAR NUCLEI, SOLID-STATE NMR, HYPERBOLIC SECANT PULSES, DOUBLE FREQUENCY SWEEPS, NATURAL-ABUNDANCE, SENSITIVITY ENHANCEMENT, SATELLITE TRANSITIONS, POPULATION TRANSFER, COUPLING-CONSTANTS, SPECTRA",
author = "O'Dell, {L. A.} and K. Klimm and Freitas, {J. C. C.} and Kohn, {S. C.} and Smith, {Mark E.}",
year = "2009",
month = feb,
day = "1",
doi = "10.1007/s00723-008-0159-8",
language = "English",
volume = "35",
pages = "247--259",
journal = "Applied Magnetic Resonance",
issn = "1613-7507",
publisher = "Springer Wien",
number = "2",

}

RIS

TY - JOUR

T1 - (33)S MAS NMR of a disordered sulfur-doped silicate: signal enhancement via RAPT, QCPMG and adiabatic pulses

AU - O'Dell, L. A.

AU - Klimm, K.

AU - Freitas, J. C. C.

AU - Kohn, S. C.

AU - Smith, Mark E.

PY - 2009/2/1

Y1 - 2009/2/1

N2 - Three different signal enhancement techniques have been applied to (33)S magic-angle spinning nuclear magnetic resonance (MAS NMR) of a disordered silicate containing 1.15 wt% (33)S. Partial saturation of the satellite transitions was achieved using a rotor-assisted population transfer (RAPT) pulse sequence, resulting in a signal enhancement of 1.63, albeit with a slight distortion of the line shape due to selective excitation. Adiabatic inversion of the satellite transitions by various amplitude-and frequency-modulated pulse shapes (such as hyperbolic secant and wideband uniform-rate smooth truncation) was also attempted, resulting in a signal enhancement of up to 1.85, with no apparent line shape distortion. Quadrupolar Carr-Purcell-Meiboom-Gill (QCPMG) and RAPT-QCPMG sequences were also used, both of which yielded spikelet spectra that accurately reflected the MAS line shape with a greatly improved signal-to-noise ratio. It is hoped that this study demonstrates that (33)S solid-state MAS NMR is now feasible even on disordered, low-sulfur-content systems.

AB - Three different signal enhancement techniques have been applied to (33)S magic-angle spinning nuclear magnetic resonance (MAS NMR) of a disordered silicate containing 1.15 wt% (33)S. Partial saturation of the satellite transitions was achieved using a rotor-assisted population transfer (RAPT) pulse sequence, resulting in a signal enhancement of 1.63, albeit with a slight distortion of the line shape due to selective excitation. Adiabatic inversion of the satellite transitions by various amplitude-and frequency-modulated pulse shapes (such as hyperbolic secant and wideband uniform-rate smooth truncation) was also attempted, resulting in a signal enhancement of up to 1.85, with no apparent line shape distortion. Quadrupolar Carr-Purcell-Meiboom-Gill (QCPMG) and RAPT-QCPMG sequences were also used, both of which yielded spikelet spectra that accurately reflected the MAS line shape with a greatly improved signal-to-noise ratio. It is hoped that this study demonstrates that (33)S solid-state MAS NMR is now feasible even on disordered, low-sulfur-content systems.

KW - INTEGER QUADRUPOLAR NUCLEI

KW - SOLID-STATE NMR

KW - HYPERBOLIC SECANT PULSES

KW - DOUBLE FREQUENCY SWEEPS

KW - NATURAL-ABUNDANCE

KW - SENSITIVITY ENHANCEMENT

KW - SATELLITE TRANSITIONS

KW - POPULATION TRANSFER

KW - COUPLING-CONSTANTS

KW - SPECTRA

U2 - 10.1007/s00723-008-0159-8

DO - 10.1007/s00723-008-0159-8

M3 - Journal article

VL - 35

SP - 247

EP - 259

JO - Applied Magnetic Resonance

JF - Applied Magnetic Resonance

SN - 1613-7507

IS - 2

ER -