87Sr, 119Sn, 127I Single and {1H/19F}-Double Resonance Solid-State NMR Experiments: Application to Inorganic Materials and Nanobuilding Blocks

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87Sr, 119Sn, 127I Single and {1H/19F}-Double Resonance Solid-State NMR Experiments: Application to Inorganic Materials and Nanobuilding Blocks. / Laurencin, D.; Ribot, F.; Gervais, C. et al.
In: ChemistrySelect, Vol. 1, No. 15, 16.09.2016, p. 4509-4519.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Laurencin, D, Ribot, F, Gervais, C, Wright, AJ, Baker, AR, Campayo, L, Hanna, JV, Iuga, D, Smith, ME, Nedelec, J-M, Renaudin, G & Bonhomme, C 2016, '87Sr, 119Sn, 127I Single and {1H/19F}-Double Resonance Solid-State NMR Experiments: Application to Inorganic Materials and Nanobuilding Blocks', ChemistrySelect, vol. 1, no. 15, pp. 4509-4519. https://doi.org/10.1002/slct.201600805

APA

Laurencin, D., Ribot, F., Gervais, C., Wright, A. J., Baker, A. R., Campayo, L., Hanna, J. V., Iuga, D., Smith, M. E., Nedelec, J.-M., Renaudin, G., & Bonhomme, C. (2016). 87Sr, 119Sn, 127I Single and {1H/19F}-Double Resonance Solid-State NMR Experiments: Application to Inorganic Materials and Nanobuilding Blocks. ChemistrySelect, 1(15), 4509-4519. https://doi.org/10.1002/slct.201600805

Vancouver

Laurencin D, Ribot F, Gervais C, Wright AJ, Baker AR, Campayo L et al. 87Sr, 119Sn, 127I Single and {1H/19F}-Double Resonance Solid-State NMR Experiments: Application to Inorganic Materials and Nanobuilding Blocks. ChemistrySelect. 2016 Sept 16;1(15):4509-4519. doi: 10.1002/slct.201600805

Author

Laurencin, D. ; Ribot, F. ; Gervais, C. et al. / 87Sr, 119Sn, 127I Single and {1H/19F}-Double Resonance Solid-State NMR Experiments: Application to Inorganic Materials and Nanobuilding Blocks. In: ChemistrySelect. 2016 ; Vol. 1, No. 15. pp. 4509-4519.

Bibtex

@article{ea86fc4cefbf4569bbf59e3c8e824541,

title = "87Sr, 119Sn, 127I Single and {1H/19F}-Double Resonance Solid-State NMR Experiments: Application to Inorganic Materials and Nanobuilding Blocks",

abstract = "87Sr, 127I and 119Sn wideline NMR spectroscopy was successfully applied to inorganic and hybrid materials: (i) Sr derivatives of medicinal interest (Sr-malonate, Sr-pyrophosphates, mixed Ca,Sr-fluoroapatites); (ii) apatitic structures acting as host matrices for iodine; and (iii) Sn-derived oxo-clusters which can be used as inorganic nanobuilding blocks. The BRAIN (BRoadband Adiabatic INversion) CP (Cross Polarization) approach (by Schurko et al.) was applied to a non integer quadrupolar nucleus (87Sr, I=9/2). The sequence was used in combination with WURST (Wideband Uniform-Rate Smooth-Truncation) QCPMG (Quadrupolar Carr-Purcell Meiboom-Gill) for optimal sensitivity. We showed that 127I WURST QCPMG experiments were sufficiently sensitive to allow rapid characterization of the incorporation of iodide (I−) anions in lead vanadate/phosphate apatites, and that 127I acted as a sensitive probe for the description of local disorder. 1H/19F → 119Sn BRAIN CP was successfully applied to the detailed characterization of tin oxo-clusters, using 1H and 19F as spin baths. We demonstrated that BRAIN CP can be effectively used as a tool of spectral editing leading to the estimation of spatial proximities between 119Sn and 1H/19F nuclei. {\textcopyright} 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

keywords = "BRAIN CP, Iodo/fluoroapatite, Strontium malonate/boronate, Tin oxo-clusters, Wideline NMR (87Sr, 119Sn, 127I), WURST QCPMG",

author = "D. Laurencin and F. Ribot and C. Gervais and A.J. Wright and A.R. Baker and L. Campayo and J.V. Hanna and D. Iuga and M.E. Smith and J.-M. Nedelec and G. Renaudin and C. Bonhomme",

year = "2016",

month = sep,

day = "16",

doi = "10.1002/slct.201600805",

language = "English",

volume = "1",

pages = "4509--4519",

journal = "ChemistrySelect",

issn = "2365-6549",

publisher = "Wiley Blackwell",

number = "15",

}

RIS

TY - JOUR

T1 - 87Sr, 119Sn, 127I Single and {1H/19F}-Double Resonance Solid-State NMR Experiments: Application to Inorganic Materials and Nanobuilding Blocks

AU - Laurencin, D.

AU - Ribot, F.

AU - Gervais, C.

AU - Wright, A.J.

AU - Baker, A.R.

AU - Campayo, L.

AU - Hanna, J.V.

AU - Iuga, D.

AU - Smith, M.E.

AU - Nedelec, J.-M.

AU - Renaudin, G.

AU - Bonhomme, C.

PY - 2016/9/16

Y1 - 2016/9/16

N2 - 87Sr, 127I and 119Sn wideline NMR spectroscopy was successfully applied to inorganic and hybrid materials: (i) Sr derivatives of medicinal interest (Sr-malonate, Sr-pyrophosphates, mixed Ca,Sr-fluoroapatites); (ii) apatitic structures acting as host matrices for iodine; and (iii) Sn-derived oxo-clusters which can be used as inorganic nanobuilding blocks. The BRAIN (BRoadband Adiabatic INversion) CP (Cross Polarization) approach (by Schurko et al.) was applied to a non integer quadrupolar nucleus (87Sr, I=9/2). The sequence was used in combination with WURST (Wideband Uniform-Rate Smooth-Truncation) QCPMG (Quadrupolar Carr-Purcell Meiboom-Gill) for optimal sensitivity. We showed that 127I WURST QCPMG experiments were sufficiently sensitive to allow rapid characterization of the incorporation of iodide (I−) anions in lead vanadate/phosphate apatites, and that 127I acted as a sensitive probe for the description of local disorder. 1H/19F → 119Sn BRAIN CP was successfully applied to the detailed characterization of tin oxo-clusters, using 1H and 19F as spin baths. We demonstrated that BRAIN CP can be effectively used as a tool of spectral editing leading to the estimation of spatial proximities between 119Sn and 1H/19F nuclei. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

AB - 87Sr, 127I and 119Sn wideline NMR spectroscopy was successfully applied to inorganic and hybrid materials: (i) Sr derivatives of medicinal interest (Sr-malonate, Sr-pyrophosphates, mixed Ca,Sr-fluoroapatites); (ii) apatitic structures acting as host matrices for iodine; and (iii) Sn-derived oxo-clusters which can be used as inorganic nanobuilding blocks. The BRAIN (BRoadband Adiabatic INversion) CP (Cross Polarization) approach (by Schurko et al.) was applied to a non integer quadrupolar nucleus (87Sr, I=9/2). The sequence was used in combination with WURST (Wideband Uniform-Rate Smooth-Truncation) QCPMG (Quadrupolar Carr-Purcell Meiboom-Gill) for optimal sensitivity. We showed that 127I WURST QCPMG experiments were sufficiently sensitive to allow rapid characterization of the incorporation of iodide (I−) anions in lead vanadate/phosphate apatites, and that 127I acted as a sensitive probe for the description of local disorder. 1H/19F → 119Sn BRAIN CP was successfully applied to the detailed characterization of tin oxo-clusters, using 1H and 19F as spin baths. We demonstrated that BRAIN CP can be effectively used as a tool of spectral editing leading to the estimation of spatial proximities between 119Sn and 1H/19F nuclei. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

KW - BRAIN CP

KW - Iodo/fluoroapatite

KW - Strontium malonate/boronate

KW - Tin oxo-clusters

KW - Wideline NMR (87Sr, 119Sn, 127I)

KW - WURST QCPMG

U2 - 10.1002/slct.201600805

DO - 10.1002/slct.201600805

M3 - Journal article

VL - 1

SP - 4509

EP - 4519

JO - ChemistrySelect

JF - ChemistrySelect

SN - 2365-6549

IS - 15

ER -

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