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A 1,2,3,4,5-pentaphenylferrocene-stoppered rotaxane capable of electrochemical anion recognition

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A 1,2,3,4,5-pentaphenylferrocene-stoppered rotaxane capable of electrochemical anion recognition. / Evans, Nicholas H.; Serpell, Christopher J.; White, Nicholas G. et al.
In: Chemistry - A European Journal, Vol. 17, No. 44, 24.10.2011, p. 12347-12354.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Evans, NH, Serpell, CJ, White, NG & Beer, PD 2011, 'A 1,2,3,4,5-pentaphenylferrocene-stoppered rotaxane capable of electrochemical anion recognition', Chemistry - A European Journal, vol. 17, no. 44, pp. 12347-12354. https://doi.org/10.1002/chem.201101811

APA

Evans, N. H., Serpell, C. J., White, N. G., & Beer, P. D. (2011). A 1,2,3,4,5-pentaphenylferrocene-stoppered rotaxane capable of electrochemical anion recognition. Chemistry - A European Journal, 17(44), 12347-12354. https://doi.org/10.1002/chem.201101811

Vancouver

Evans NH, Serpell CJ, White NG, Beer PD. A 1,2,3,4,5-pentaphenylferrocene-stoppered rotaxane capable of electrochemical anion recognition. Chemistry - A European Journal. 2011 Oct 24;17(44):12347-12354. doi: 10.1002/chem.201101811

Author

Evans, Nicholas H. ; Serpell, Christopher J. ; White, Nicholas G. et al. / A 1,2,3,4,5-pentaphenylferrocene-stoppered rotaxane capable of electrochemical anion recognition. In: Chemistry - A European Journal. 2011 ; Vol. 17, No. 44. pp. 12347-12354.

Bibtex

@article{f1dc7a0c00bd49f2b53d281cd46f2a1c,
title = "A 1,2,3,4,5-pentaphenylferrocene-stoppered rotaxane capable of electrochemical anion recognition",
abstract = "The chloride anion templated synthesis of an electrochemical anion sensory interlocked host system, prepared by the integration of redox-active 1,2,3,4,5-pentaphenylferrocene stopper groups into the structure of a rotaxane capable of binding anionic guests is described. Extensive H-1 NMR and electrochemical titration investigations were used to probe the anion recognition and sensing properties of the rotaxane, compared to the axle and model system components. A characteristic electrochemical response was observed for chloride binding by the rotaxane, which was attributed to the topologically constrained cavity of the interlocked host molecule.",
keywords = "anions, electrochemistry, molecular recognition, rotaxanes, supramolecular chemistry, TEMPLATED FORMATION, AQUEOUS-MEDIA, RECEPTORS, FERROCENE, CHLORIDE, INDOLOCARBAZOLE, CATENANES, SYSTEMS, UREAS",
author = "Evans, {Nicholas H.} and Serpell, {Christopher J.} and White, {Nicholas G.} and Beer, {Paul D.}",
year = "2011",
month = oct,
day = "24",
doi = "10.1002/chem.201101811",
language = "English",
volume = "17",
pages = "12347--12354",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag",
number = "44",

}

RIS

TY - JOUR

T1 - A 1,2,3,4,5-pentaphenylferrocene-stoppered rotaxane capable of electrochemical anion recognition

AU - Evans, Nicholas H.

AU - Serpell, Christopher J.

AU - White, Nicholas G.

AU - Beer, Paul D.

PY - 2011/10/24

Y1 - 2011/10/24

N2 - The chloride anion templated synthesis of an electrochemical anion sensory interlocked host system, prepared by the integration of redox-active 1,2,3,4,5-pentaphenylferrocene stopper groups into the structure of a rotaxane capable of binding anionic guests is described. Extensive H-1 NMR and electrochemical titration investigations were used to probe the anion recognition and sensing properties of the rotaxane, compared to the axle and model system components. A characteristic electrochemical response was observed for chloride binding by the rotaxane, which was attributed to the topologically constrained cavity of the interlocked host molecule.

AB - The chloride anion templated synthesis of an electrochemical anion sensory interlocked host system, prepared by the integration of redox-active 1,2,3,4,5-pentaphenylferrocene stopper groups into the structure of a rotaxane capable of binding anionic guests is described. Extensive H-1 NMR and electrochemical titration investigations were used to probe the anion recognition and sensing properties of the rotaxane, compared to the axle and model system components. A characteristic electrochemical response was observed for chloride binding by the rotaxane, which was attributed to the topologically constrained cavity of the interlocked host molecule.

KW - anions

KW - electrochemistry

KW - molecular recognition

KW - rotaxanes

KW - supramolecular chemistry

KW - TEMPLATED FORMATION

KW - AQUEOUS-MEDIA

KW - RECEPTORS

KW - FERROCENE

KW - CHLORIDE

KW - INDOLOCARBAZOLE

KW - CATENANES

KW - SYSTEMS

KW - UREAS

U2 - 10.1002/chem.201101811

DO - 10.1002/chem.201101811

M3 - Journal article

VL - 17

SP - 12347

EP - 12354

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 44

ER -