Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
}
TY - JOUR
T1 - A [2]catenane displaying pirouetting motion triggered by debenzylation and locked by chloride anion recognition
AU - Evans, Nicholas H.
AU - Serpell, Christopher J.
AU - Beer, Paul D.
PY - 2011/7
Y1 - 2011/7
N2 - Chloride locks the rings: Debenzylation of a chloride-templated N-benzyl pyridinium catenane, allows for a 180° “pirouetting” of the rings in the resulting neutral pyridyl catenane (see scheme). The catenane may be returned to its original co-conformation by chloride recognition as evidenced in solution and in the solid state.
AB - Chloride locks the rings: Debenzylation of a chloride-templated N-benzyl pyridinium catenane, allows for a 180° “pirouetting” of the rings in the resulting neutral pyridyl catenane (see scheme). The catenane may be returned to its original co-conformation by chloride recognition as evidenced in solution and in the solid state.
KW - anions
KW - catenanes
KW - molecular devices
KW - supramolecular chemistry
KW - template synthesis
KW - SELECTIVITY
KW - ROTAXANE
KW - RING
U2 - 10.1002/chem.201101033
DO - 10.1002/chem.201101033
M3 - Journal article
VL - 17
SP - 7734
EP - 7738
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
SN - 0947-6539
IS - 28
ER -