Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - A fourier-transform infrared and laster-raman spectroscopic study of 4,4'-bipyridyl transition metal (II) tetracyanonickelate ciathrates.
AU - Akyüz, Sevim
AU - Akyüz, Tanil
AU - Davies, J. Eric D.
PY - 1996/3
Y1 - 1996/3
N2 - The FT-IR and Raman spectra are reported of M(4,4-bipyridyl)Ni(CN)4·nG (where M = Mn, Fe, Co, Cu or Zn and G = benzene or aniline;n = 0–2) clathrates. The host structure consists of a three-dimensional rigid lattice formed by infinite polymeric layers of {M-Ni(CN)4} and 4,4-bipyridyl bridges between the metal (M) atoms of the adjacent polymeric layers. Bidentate 4,4-bipyridyl molecules are found to be centrosymmetric in the structure.
AB - The FT-IR and Raman spectra are reported of M(4,4-bipyridyl)Ni(CN)4·nG (where M = Mn, Fe, Co, Cu or Zn and G = benzene or aniline;n = 0–2) clathrates. The host structure consists of a three-dimensional rigid lattice formed by infinite polymeric layers of {M-Ni(CN)4} and 4,4-bipyridyl bridges between the metal (M) atoms of the adjacent polymeric layers. Bidentate 4,4-bipyridyl molecules are found to be centrosymmetric in the structure.
KW - Tetracyanonickelate compounds - benzene clathrate - aniline clathrate - IR and Raman spectra - 4
KW - 4-bipyridyl complexes
U2 - 10.1007/BF01029935
DO - 10.1007/BF01029935
M3 - Journal article
VL - 26
SP - 111
EP - 117
JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry
JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry
SN - 0923-0750
IS - 1-3
ER -