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A homochiral 2D copper(II) coordination framework

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<mark>Journal publication date</mark>1/02/2009
<mark>Journal</mark>European Journal of Inorganic Chemistry
Issue number6
Volume2009
Number of pages4
Pages (from-to)717-720
Publication StatusPublished
<mark>Original language</mark>English

Abstract

Reaction of copper(II) salts with (S)-phenylethylaminodiacetate [(S)-peadaa] results in the 2D coordination network (S)-[Cu(peadaa)]n (space group P21), which displays an unusual Cu···Cu connectivity mode. Solid-state circular dichroism (CD) indicates a strong interaction between the ligand chiral centre and the metal centres, whereas magnetic measurements show both antiferromagnetic coupling and strong ligand field effects. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)