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A laser flash photolysis study of nitrous acid in the aqueous phase

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A laser flash photolysis study of nitrous acid in the aqueous phase. / Ouyang, B; Dong, WB; Hou, HQ.

In: Chemical Physics Letters, Vol. 402, No. 4-6, 04.02.2005, p. 306-311.

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Ouyang, B, Dong, WB & Hou, HQ 2005, 'A laser flash photolysis study of nitrous acid in the aqueous phase', Chemical Physics Letters, vol. 402, no. 4-6, pp. 306-311. https://doi.org/10.1016/j.cplett.2004.12.054

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Ouyang, B ; Dong, WB ; Hou, HQ. / A laser flash photolysis study of nitrous acid in the aqueous phase. In: Chemical Physics Letters. 2005 ; Vol. 402, No. 4-6. pp. 306-311.

Bibtex

@article{c8c3f5e2fc004911be0d20a66eddceed,
title = "A laser flash photolysis study of nitrous acid in the aqueous phase",
abstract = "The OH quantum yield from the photolysis of nitrous acid in the aqueous phase by the 355 nm light was measured to be 0.25 ± 0.03. OH radical thus formed reacted readily with HNO2 to produce NO2, which sequentially reacted with HNO2 to form the HNO2–NO2 adduct. The NO2 + HNO2 reaction was reversible with a forward rate constant of 3.76 × 107 dm3 mol−1 s−1 and a backward rate constant of 1.06 × 105 s−1. Decay of the HNO2–NO2 adduct would most likely generate HNO3 and NO at a rate constant of 3.0 × 103 s−1.",
author = "B Ouyang and WB Dong and HQ Hou",
year = "2005",
month = feb,
day = "4",
doi = "10.1016/j.cplett.2004.12.054",
language = "English",
volume = "402",
pages = "306--311",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "4-6",

}

RIS

TY - JOUR

T1 - A laser flash photolysis study of nitrous acid in the aqueous phase

AU - Ouyang, B

AU - Dong, WB

AU - Hou, HQ

PY - 2005/2/4

Y1 - 2005/2/4

N2 - The OH quantum yield from the photolysis of nitrous acid in the aqueous phase by the 355 nm light was measured to be 0.25 ± 0.03. OH radical thus formed reacted readily with HNO2 to produce NO2, which sequentially reacted with HNO2 to form the HNO2–NO2 adduct. The NO2 + HNO2 reaction was reversible with a forward rate constant of 3.76 × 107 dm3 mol−1 s−1 and a backward rate constant of 1.06 × 105 s−1. Decay of the HNO2–NO2 adduct would most likely generate HNO3 and NO at a rate constant of 3.0 × 103 s−1.

AB - The OH quantum yield from the photolysis of nitrous acid in the aqueous phase by the 355 nm light was measured to be 0.25 ± 0.03. OH radical thus formed reacted readily with HNO2 to produce NO2, which sequentially reacted with HNO2 to form the HNO2–NO2 adduct. The NO2 + HNO2 reaction was reversible with a forward rate constant of 3.76 × 107 dm3 mol−1 s−1 and a backward rate constant of 1.06 × 105 s−1. Decay of the HNO2–NO2 adduct would most likely generate HNO3 and NO at a rate constant of 3.0 × 103 s−1.

U2 - 10.1016/j.cplett.2004.12.054

DO - 10.1016/j.cplett.2004.12.054

M3 - Journal article

VL - 402

SP - 306

EP - 311

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 4-6

ER -