Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
}
TY - JOUR
T1 - A meta-xylenediamide macrocycle containing rotaxane anion host system constructed by a new synthetic clipping methodology
AU - Evans, Nicholas H.
AU - Serpell, Christopher J.
AU - Beer, Paul D.
PY - 2011/10/1
Y1 - 2011/10/1
N2 - A novel rotaxane containing a meta-xylenediamide macrocycle is prepared by a new clipping methodology. Upon anion metathesis to the non-coordinating hexafluorophosphate salt, the rotaxane host system was shown to bind chloride and bromide anions more strongly than the basic oxoanions dihydrogen phosphate and acetate in the competitive solvent system 1:1 CDCl(3):CD(3)OD.
AB - A novel rotaxane containing a meta-xylenediamide macrocycle is prepared by a new clipping methodology. Upon anion metathesis to the non-coordinating hexafluorophosphate salt, the rotaxane host system was shown to bind chloride and bromide anions more strongly than the basic oxoanions dihydrogen phosphate and acetate in the competitive solvent system 1:1 CDCl(3):CD(3)OD.
KW - AQUEOUS-MEDIA
KW - CHLORIDE
KW - TEMPLATION
KW - RECEPTOR
U2 - 10.1039/c1nj20109c
DO - 10.1039/c1nj20109c
M3 - Journal article
VL - 35
SP - 2047
EP - 2053
JO - New Journal of Chemistry
JF - New Journal of Chemistry
SN - 1144-0546
IS - 10
ER -