A multispectroscopic structural study of lead silicate glasses over an extended range of compositions

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A multispectroscopic structural study of lead silicate glasses over an extended range of compositions. / Feller, Steve; Lodden, G.; Riley, A. et al.
In: Journal of Non-Crystalline Solids, Vol. 356, No. 6-8, 01.03.2010, p. 304-313.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Feller, S, Lodden, G, Riley, A, Edwards, T, Croskrey, J, Schue, A, Liss, D, Stentz, D, Blair, S, Kelley, M, Smith, G, Singleton, S, Affatigato, M, Holland, D, Smith, ME, Kamitsos, EI, Varsamis, CPE & Ioannou, E 2010, 'A multispectroscopic structural study of lead silicate glasses over an extended range of compositions', Journal of Non-Crystalline Solids, vol. 356, no. 6-8, pp. 304-313. https://doi.org/10.1016/j.jnoncrysol.2009.12.003

APA

Feller, S., Lodden, G., Riley, A., Edwards, T., Croskrey, J., Schue, A., Liss, D., Stentz, D., Blair, S., Kelley, M., Smith, G., Singleton, S., Affatigato, M., Holland, D., Smith, M. E., Kamitsos, E. I., Varsamis, C. P. E., & Ioannou, E. (2010). A multispectroscopic structural study of lead silicate glasses over an extended range of compositions. Journal of Non-Crystalline Solids, 356(6-8), 304-313. https://doi.org/10.1016/j.jnoncrysol.2009.12.003

Vancouver

Feller S, Lodden G, Riley A, Edwards T, Croskrey J, Schue A et al. A multispectroscopic structural study of lead silicate glasses over an extended range of compositions. Journal of Non-Crystalline Solids. 2010 Mar 1;356(6-8):304-313. doi: 10.1016/j.jnoncrysol.2009.12.003

Author

Feller, Steve ; Lodden, G. ; Riley, A. et al. / A multispectroscopic structural study of lead silicate glasses over an extended range of compositions. In: Journal of Non-Crystalline Solids. 2010 ; Vol. 356, No. 6-8. pp. 304-313.

Bibtex

@article{46e349428cd444e4b0bb1c1bdab7e47b,

title = "A multispectroscopic structural study of lead silicate glasses over an extended range of compositions",

abstract = "A series of lead silicate glasses, spanning the broadest reported range of lead contents (up to 83 mol% PbO), were prepared, on which the following spectroscopic observations were made: 29Si magic angle spinning nuclear magnetic resonance, time of flight mass spectroscopy, raman spectroscopy and fourier transform infrared spectroscopy. For bulk, splat-quenched samples, infrared results indicate that the lever rule is approximately followed until about 60 mol% PbO, though with considerable dissociation of the stoichiometric groups into silicate units with lesser and greater numbers of non-bridging oxygens. For roller-quenched samples, nuclear magnetic resonance data are consistent with a statistical distribution up to this lead concentration. Above 60 mol% PbO, added oxygen remains associated with lead to form a separate lead oxide glass network. The evidence for this comes from each of the spectroscopic techniques employed. A quantitative distribution of PbO is given.",

keywords = "Diffraction and scattering measurements, Raman scattering , Glass formation, Glass transition, Glasses, Nuclear magnetic (and quadrupole) resonance, Mass spectroscopy , Modeling and simulation , Optical properties , FTIR measurements, Oxide glasses, Silicates, Resonance methods , NMR, MAS NMR and NQR , Structure, Short-range order, Thermal properties",

author = "Steve Feller and G. Lodden and A. Riley and T. Edwards and J. Croskrey and A. Schue and D. Liss and D. Stentz and S. Blair and M. Kelley and G. Smith and S. Singleton and Mario Affatigato and D. Holland and Smith, {Mark E.} and Kamitsos, {E. I.} and Varsamis, {C. P. E.} and E. Ioannou",

year = "2010",

month = mar,

day = "1",

doi = "10.1016/j.jnoncrysol.2009.12.003",

language = "English",

volume = "356",

pages = "304--313",

journal = "Journal of Non-Crystalline Solids",

issn = "0022-3093",

publisher = "Elsevier",

number = "6-8",

}

RIS

TY - JOUR

T1 - A multispectroscopic structural study of lead silicate glasses over an extended range of compositions

AU - Feller, Steve

AU - Lodden, G.

AU - Riley, A.

AU - Edwards, T.

AU - Croskrey, J.

AU - Schue, A.

AU - Liss, D.

AU - Stentz, D.

AU - Blair, S.

AU - Kelley, M.

AU - Smith, G.

AU - Singleton, S.

AU - Affatigato, Mario

AU - Holland, D.

AU - Smith, Mark E.

AU - Kamitsos, E. I.

AU - Varsamis, C. P. E.

AU - Ioannou, E.

PY - 2010/3/1

Y1 - 2010/3/1

N2 - A series of lead silicate glasses, spanning the broadest reported range of lead contents (up to 83 mol% PbO), were prepared, on which the following spectroscopic observations were made: 29Si magic angle spinning nuclear magnetic resonance, time of flight mass spectroscopy, raman spectroscopy and fourier transform infrared spectroscopy. For bulk, splat-quenched samples, infrared results indicate that the lever rule is approximately followed until about 60 mol% PbO, though with considerable dissociation of the stoichiometric groups into silicate units with lesser and greater numbers of non-bridging oxygens. For roller-quenched samples, nuclear magnetic resonance data are consistent with a statistical distribution up to this lead concentration. Above 60 mol% PbO, added oxygen remains associated with lead to form a separate lead oxide glass network. The evidence for this comes from each of the spectroscopic techniques employed. A quantitative distribution of PbO is given.

AB - A series of lead silicate glasses, spanning the broadest reported range of lead contents (up to 83 mol% PbO), were prepared, on which the following spectroscopic observations were made: 29Si magic angle spinning nuclear magnetic resonance, time of flight mass spectroscopy, raman spectroscopy and fourier transform infrared spectroscopy. For bulk, splat-quenched samples, infrared results indicate that the lever rule is approximately followed until about 60 mol% PbO, though with considerable dissociation of the stoichiometric groups into silicate units with lesser and greater numbers of non-bridging oxygens. For roller-quenched samples, nuclear magnetic resonance data are consistent with a statistical distribution up to this lead concentration. Above 60 mol% PbO, added oxygen remains associated with lead to form a separate lead oxide glass network. The evidence for this comes from each of the spectroscopic techniques employed. A quantitative distribution of PbO is given.

KW - Diffraction and scattering measurements

KW - Raman scattering

KW - Glass formation

KW - Glass transition

KW - Glasses

KW - Nuclear magnetic (and quadrupole) resonance

KW - Mass spectroscopy

KW - Modeling and simulation

KW - Optical properties

KW - FTIR measurements

KW - Oxide glasses

KW - Silicates

KW - Resonance methods

KW - NMR, MAS NMR and NQR

KW - Structure

KW - Short-range order

KW - Thermal properties

U2 - 10.1016/j.jnoncrysol.2009.12.003

DO - 10.1016/j.jnoncrysol.2009.12.003

M3 - Journal article

VL - 356

SP - 304

EP - 313

JO - Journal of Non-Crystalline Solids

JF - Journal of Non-Crystalline Solids

SN - 0022-3093

IS - 6-8

ER -

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