Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
}
TY - JOUR
T1 - A natural abundance Se-77 solid-state NMR study of inorganic compounds
AU - Kemp, Thomas F.
AU - Wong, A.
AU - Smith, Mark E.
AU - Bishop, P. T.
AU - Carthey, N.
PY - 2008/11/1
Y1 - 2008/11/1
N2 - Various inorganic selenium-based compounds were analysed by Se-77 solid-state NMR, and a distinct difference in chemical shift ranges for compounds where selenium is present as selenide (Se2-) ionically and covalently bonded systems was observed. The selenides exhibit a shift range of approximately -700 to -100 ppm, as opposed to 700 to 1600 ppm for the Compounds where there tends to be more direct covalent bonding to the selenium. The anisotropic hyperfine shift observed in NbSe2 is shown to be axially symmetric, where the Hit component is found to be normal to the Se3-trigonal plane. (c) 2008 Elsevier Inc. All rights reserved.
AB - Various inorganic selenium-based compounds were analysed by Se-77 solid-state NMR, and a distinct difference in chemical shift ranges for compounds where selenium is present as selenide (Se2-) ionically and covalently bonded systems was observed. The selenides exhibit a shift range of approximately -700 to -100 ppm, as opposed to 700 to 1600 ppm for the Compounds where there tends to be more direct covalent bonding to the selenium. The anisotropic hyperfine shift observed in NbSe2 is shown to be axially symmetric, where the Hit component is found to be normal to the Se3-trigonal plane. (c) 2008 Elsevier Inc. All rights reserved.
KW - Se-77 NMR, Inorganic selenides, Selenates, Shift range, Hyperfine interactions
U2 - 10.1016/j.ssnmr.2008.10.003
DO - 10.1016/j.ssnmr.2008.10.003
M3 - Journal article
VL - 34
SP - 224
EP - 227
JO - Solid State Nuclear Magnetic Resonance
JF - Solid State Nuclear Magnetic Resonance
SN - 1527-3326
IS - 4
ER -