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A non-photochemical route to synthesize simple benzo[1,2-b:4,3-b′] dithiophenes: FeCl3-mediated cyclization of dithienyl ethenes

Research output: Contribution to Journal/MagazineJournal articlepeer-review

Published
  • Silvia Cauteruccio
  • Davide Dova
  • Claudia Graiff
  • Claudio Carrara
  • Julien Doulcet
  • G. Richard Stephenson
  • Emanuela Licandro
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<mark>Journal publication date</mark>30/06/2014
<mark>Journal</mark>New Journal of Chemistry
Issue number6
Volume38
Number of pages4
Pages (from-to)2241-2244
Publication StatusPublished
<mark>Original language</mark>English

Abstract

The FeCl3-mediated cyclization of α,α′- disubstituted Z-alkenes 1 is reported as a general and non-photochemical route to synthesize benzo[1,2-b:4,3-b′]dithiophene (BDT) derivatives 2, achievable in good yields starting from cheap and easily available materials. The influence of the temperature and the nature of the substituents on the scope and limitations of this methodology is also reported. This journal is