Home > Research > Publications & Outputs > A Si-29 MAS NMR study of silicate glasses with ...

Research

Text available via DOI:

View graph of relations

A Si-29 MAS NMR study of silicate glasses with a high lithium content

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Published

Standard

A Si-29 MAS NMR study of silicate glasses with a high lithium content. / Larson, C.; Doerr, J.; Affatigato, M. et al.
In: Journal of Physics: Condensed Matter, Vol. 18, No. 49, 2006, p. 11323-11331.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Larson, C, Doerr, J, Affatigato, M, Feller, S, Holland, D & Smith, ME 2006, 'A Si-29 MAS NMR study of silicate glasses with a high lithium content', Journal of Physics: Condensed Matter, vol. 18, no. 49, pp. 11323-11331. https://doi.org/10.1088/0953-8984/18/49/023

APA

Larson, C., Doerr, J., Affatigato, M., Feller, S., Holland, D., & Smith, M. E. (2006). A Si-29 MAS NMR study of silicate glasses with a high lithium content. Journal of Physics: Condensed Matter, 18(49), 11323-11331. https://doi.org/10.1088/0953-8984/18/49/023

Vancouver

Larson C, Doerr J, Affatigato M, Feller S, Holland D, Smith ME. A Si-29 MAS NMR study of silicate glasses with a high lithium content. Journal of Physics: Condensed Matter. 2006;18(49):11323-11331. doi: 10.1088/0953-8984/18/49/023

Author

Larson, C. ; Doerr, J. ; Affatigato, M. et al. / A Si-29 MAS NMR study of silicate glasses with a high lithium content. In: Journal of Physics: Condensed Matter. 2006 ; Vol. 18, No. 49. pp. 11323-11331.

Bibtex

@article{c263112b618f463cbe3109ad0fad7c1d,
title = "A Si-29 MAS NMR study of silicate glasses with a high lithium content",
abstract = "A series of lithium silicate glasses approaching the orthosilicate composition (66.7 mol% Li2O) were prepared and their Si-29 magic angle spinning nuclear magnetic resonance (NMR) recorded; this significantly extends the compositional range of glasses studied by this technique. The results indicate that the lever (binary) rule is approximately followed, though with considerable dissociation of the stoichiometric groups into silicate units with lesser and greater numbers of non-bridging oxygens according to the relation 2Q(n)-> Q(n+1)->Q(n-1). The NMR results were compared with the Raman study of Umesaki et al (1988 J. Non-Cryst. Solids 106 77-80) on the same system. Volumes per mol silica, determined from the experimental densities, were also used to test the structural results from the present NMR observations.",
author = "C. Larson and J. Doerr and M. Affatigato and S. Feller and D. Holland and Smith, {Mark E.}",
year = "2006",
doi = "10.1088/0953-8984/18/49/023",
language = "English",
volume = "18",
pages = "11323--11331",
journal = "Journal of Physics: Condensed Matter",
issn = "0953-8984",
publisher = "IOP Publishing Ltd",
number = "49",

}

RIS

TY - JOUR

T1 - A Si-29 MAS NMR study of silicate glasses with a high lithium content

AU - Larson, C.

AU - Doerr, J.

AU - Affatigato, M.

AU - Feller, S.

AU - Holland, D.

AU - Smith, Mark E.

PY - 2006

Y1 - 2006

N2 - A series of lithium silicate glasses approaching the orthosilicate composition (66.7 mol% Li2O) were prepared and their Si-29 magic angle spinning nuclear magnetic resonance (NMR) recorded; this significantly extends the compositional range of glasses studied by this technique. The results indicate that the lever (binary) rule is approximately followed, though with considerable dissociation of the stoichiometric groups into silicate units with lesser and greater numbers of non-bridging oxygens according to the relation 2Q(n)-> Q(n+1)->Q(n-1). The NMR results were compared with the Raman study of Umesaki et al (1988 J. Non-Cryst. Solids 106 77-80) on the same system. Volumes per mol silica, determined from the experimental densities, were also used to test the structural results from the present NMR observations.

AB - A series of lithium silicate glasses approaching the orthosilicate composition (66.7 mol% Li2O) were prepared and their Si-29 magic angle spinning nuclear magnetic resonance (NMR) recorded; this significantly extends the compositional range of glasses studied by this technique. The results indicate that the lever (binary) rule is approximately followed, though with considerable dissociation of the stoichiometric groups into silicate units with lesser and greater numbers of non-bridging oxygens according to the relation 2Q(n)-> Q(n+1)->Q(n-1). The NMR results were compared with the Raman study of Umesaki et al (1988 J. Non-Cryst. Solids 106 77-80) on the same system. Volumes per mol silica, determined from the experimental densities, were also used to test the structural results from the present NMR observations.

U2 - 10.1088/0953-8984/18/49/023

DO - 10.1088/0953-8984/18/49/023

M3 - Journal article

VL - 18

SP - 11323

EP - 11331

JO - Journal of Physics: Condensed Matter

JF - Journal of Physics: Condensed Matter

SN - 0953-8984

IS - 49

ER -