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A Simple and Efficient Device and Method for Measuring the Kinetics of Gas-Producing Reactions

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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A Simple and Efficient Device and Method for Measuring the Kinetics of Gas-Producing Reactions. / Slot, Thierry; Raveendran, Shiju; Rothenberg, G.
In: Angewandte Chemie International Edition, Vol. 58, No. 48, 25.11.2019, p. 17273-17276.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Slot, T, Raveendran, S & Rothenberg, G 2019, 'A Simple and Efficient Device and Method for Measuring the Kinetics of Gas-Producing Reactions', Angewandte Chemie International Edition, vol. 58, no. 48, pp. 17273-17276. https://doi.org/10.1002/anie.201911005

APA

Slot, T., Raveendran, S., & Rothenberg, G. (2019). A Simple and Efficient Device and Method for Measuring the Kinetics of Gas-Producing Reactions. Angewandte Chemie International Edition, 58(48), 17273-17276. https://doi.org/10.1002/anie.201911005

Vancouver

Slot T, Raveendran S, Rothenberg G. A Simple and Efficient Device and Method for Measuring the Kinetics of Gas-Producing Reactions. Angewandte Chemie International Edition. 2019 Nov 25;58(48):17273-17276. Epub 2019 Oct 15. doi: 10.1002/anie.201911005

Author

Slot, Thierry ; Raveendran, Shiju ; Rothenberg, G. / A Simple and Efficient Device and Method for Measuring the Kinetics of Gas-Producing Reactions. In: Angewandte Chemie International Edition. 2019 ; Vol. 58, No. 48. pp. 17273-17276.

Bibtex

@article{9f7d04e3cc2643a882c4d59d0fd954b2,
title = "A Simple and Efficient Device and Method for Measuring the Kinetics of Gas-Producing Reactions",
abstract = "We present a new device for quantifying gases or gas mixtures based on the simple principle of bubble counting. With this device, we can follow reaction kinetics down to volume step sizes of 8–12 μL. This enables the accurate determination of both time and size of these gas quanta, giving a very detailed kinetic analysis. We demonstrate this method and device using ammonia borane hydrolysis as a model reaction, obtaining Arrhenius plots with over 300 data points from a single experiment. Our device not only saves time and avoids frustration, but also offers more insight into reaction kinetics and mechanistic studies. Moreover, its simplicity and low cost open opportunities for many lab applications.",
author = "Thierry Slot and Shiju Raveendran and G Rothenberg",
year = "2019",
month = nov,
day = "25",
doi = "10.1002/anie.201911005",
language = "English",
volume = "58",
pages = "17273--17276",
journal = "Angewandte Chemie International Edition",
issn = "1433-7851",
publisher = "Wiley-VCH Verlag",
number = "48",

}

RIS

TY - JOUR

T1 - A Simple and Efficient Device and Method for Measuring the Kinetics of Gas-Producing Reactions

AU - Slot, Thierry

AU - Raveendran, Shiju

AU - Rothenberg, G

PY - 2019/11/25

Y1 - 2019/11/25

N2 - We present a new device for quantifying gases or gas mixtures based on the simple principle of bubble counting. With this device, we can follow reaction kinetics down to volume step sizes of 8–12 μL. This enables the accurate determination of both time and size of these gas quanta, giving a very detailed kinetic analysis. We demonstrate this method and device using ammonia borane hydrolysis as a model reaction, obtaining Arrhenius plots with over 300 data points from a single experiment. Our device not only saves time and avoids frustration, but also offers more insight into reaction kinetics and mechanistic studies. Moreover, its simplicity and low cost open opportunities for many lab applications.

AB - We present a new device for quantifying gases or gas mixtures based on the simple principle of bubble counting. With this device, we can follow reaction kinetics down to volume step sizes of 8–12 μL. This enables the accurate determination of both time and size of these gas quanta, giving a very detailed kinetic analysis. We demonstrate this method and device using ammonia borane hydrolysis as a model reaction, obtaining Arrhenius plots with over 300 data points from a single experiment. Our device not only saves time and avoids frustration, but also offers more insight into reaction kinetics and mechanistic studies. Moreover, its simplicity and low cost open opportunities for many lab applications.

U2 - 10.1002/anie.201911005

DO - 10.1002/anie.201911005

M3 - Journal article

VL - 58

SP - 17273

EP - 17276

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

SN - 1433-7851

IS - 48

ER -