Rights statement: © by Colin Boxall. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License. (CC BY-NC-ND 4.0)
Final published version, 226 KB, PDF document
Available under license: CC BY-NC-ND: Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
Final published version, 190 KB, PDF document
Available under license: CC BY: Creative Commons Attribution 4.0 International License
Final published version
Research output: Contribution to Journal/Magazine › Journal article › peer-review
A study of cerium extraction by TBP and TODGA using a rotating diffusion cell. / Bromley, Michael A.; Boxall, Colin.
In: Nukleonika, Vol. 60, No. 4, 12.2015, p. 859-864.Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - A study of cerium extraction by TBP and TODGA using a rotating diffusion cell
AU - Bromley, Michael A.
AU - Boxall, Colin
N1 - © by Colin Boxall. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License. (CC BY-NC-ND 4.0)
PY - 2015/12
Y1 - 2015/12
N2 - For the study of the coupled interfacial-mass transfer kinetics of, inter alia, TBP, TODGA, CyMe4-BTBP and CyMe4-BTPhen based solvent extraction processes, a new rotating diffusion cell (RDC) apparatus has been established at Lancaster University. RDC studies of Ce(IV)/TBP and Ce(III)/TODGA extraction systems have been undertaken in order to improve the understanding of the chemical and kinetic processes involved. In each case, an interesting dependency on local hydrodynamics at the solution phase boundary with results suggesting that the organic extractant molecules migrate into the aqueous phase in order to capture Ce.
AB - For the study of the coupled interfacial-mass transfer kinetics of, inter alia, TBP, TODGA, CyMe4-BTBP and CyMe4-BTPhen based solvent extraction processes, a new rotating diffusion cell (RDC) apparatus has been established at Lancaster University. RDC studies of Ce(IV)/TBP and Ce(III)/TODGA extraction systems have been undertaken in order to improve the understanding of the chemical and kinetic processes involved. In each case, an interesting dependency on local hydrodynamics at the solution phase boundary with results suggesting that the organic extractant molecules migrate into the aqueous phase in order to capture Ce.
KW - Extraction
KW - Rotating diffusion cell (RDC)
KW - SACSESS
KW - Separation
KW - TBP
KW - TODGA
U2 - 10.1515/nuka-2015-0121
DO - 10.1515/nuka-2015-0121
M3 - Journal article
AN - SCOPUS:84957592876
VL - 60
SP - 859
EP - 864
JO - Nukleonika
JF - Nukleonika
SN - 0029-5922
IS - 4
ER -