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Adsorption of 2,2′-bipyridyl onto sepiolite, attapulgite and smectite group clay minerals from anatolia: The FT-IR and FT-Raman spectra of surface and intercalated species.

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Adsorption of 2,2′-bipyridyl onto sepiolite, attapulgite and smectite group clay minerals from anatolia: The FT-IR and FT-Raman spectra of surface and intercalated species. / Akyüz, Sevim; Akyüz, Tanil; Davies, J. Eric D.
In: Journal of Inclusion Phenomena and Macrocyclic Chemistry, Vol. 18, No. 2, 06.1994, p. 123-135.

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Akyüz S, Akyüz T, Davies JED. Adsorption of 2,2′-bipyridyl onto sepiolite, attapulgite and smectite group clay minerals from anatolia: The FT-IR and FT-Raman spectra of surface and intercalated species. Journal of Inclusion Phenomena and Macrocyclic Chemistry. 1994 Jun;18(2):123-135. doi: 10.1007/BF00705816

Author

Akyüz, Sevim ; Akyüz, Tanil ; Davies, J. Eric D. / Adsorption of 2,2′-bipyridyl onto sepiolite, attapulgite and smectite group clay minerals from anatolia: The FT-IR and FT-Raman spectra of surface and intercalated species. In: Journal of Inclusion Phenomena and Macrocyclic Chemistry. 1994 ; Vol. 18, No. 2. pp. 123-135.

Bibtex

@article{e107923dd4fc4c4ebaf7164b55db4b46,
title = "Adsorption of 2,2′-bipyridyl onto sepiolite, attapulgite and smectite group clay minerals from anatolia: The FT-IR and FT-Raman spectra of surface and intercalated species.",
abstract = "The adsorption of 2,2-bipyridyl by natural sepiolite, attapulgite, hectorite, saponite and natural and ion exchanged (Mn, Fe, Co, Ni, Cu, Zn or Sn) bentonites has been investigated by FT-IR and FT-Raman spectroscopy. Spectroscopic results indicate that most of the adsorbed molecules are coordinated to either exchangeable cations (in the case of smectite group clays) or Lewis acidic centres (in the case of sepiolite and attapulgite) as bidentate ligands. The formation of monoanionic surface species has also been detected, to a relatively small extent. No physisorbed surface species has been observed. XRD patterns and UV-visible spectra of the samples are also recorded for additional information.",
keywords = "FT-IR spectroscopy - FT-Raman spectroscopy - clays - sepiolite - attapulgite - hectorite - saponite - bentonite - adsorption - 2, 2-bipyridyl",
author = "Sevim Aky{\"u}z and Tanil Aky{\"u}z and Davies, {J. Eric D.}",
year = "1994",
month = jun,
doi = "10.1007/BF00705816",
language = "English",
volume = "18",
pages = "123--135",
journal = "Journal of Inclusion Phenomena and Macrocyclic Chemistry",
issn = "0923-0750",
publisher = "Kluwer Academic Publishers",
number = "2",

}

RIS

TY - JOUR

T1 - Adsorption of 2,2′-bipyridyl onto sepiolite, attapulgite and smectite group clay minerals from anatolia: The FT-IR and FT-Raman spectra of surface and intercalated species.

AU - Akyüz, Sevim

AU - Akyüz, Tanil

AU - Davies, J. Eric D.

PY - 1994/6

Y1 - 1994/6

N2 - The adsorption of 2,2-bipyridyl by natural sepiolite, attapulgite, hectorite, saponite and natural and ion exchanged (Mn, Fe, Co, Ni, Cu, Zn or Sn) bentonites has been investigated by FT-IR and FT-Raman spectroscopy. Spectroscopic results indicate that most of the adsorbed molecules are coordinated to either exchangeable cations (in the case of smectite group clays) or Lewis acidic centres (in the case of sepiolite and attapulgite) as bidentate ligands. The formation of monoanionic surface species has also been detected, to a relatively small extent. No physisorbed surface species has been observed. XRD patterns and UV-visible spectra of the samples are also recorded for additional information.

AB - The adsorption of 2,2-bipyridyl by natural sepiolite, attapulgite, hectorite, saponite and natural and ion exchanged (Mn, Fe, Co, Ni, Cu, Zn or Sn) bentonites has been investigated by FT-IR and FT-Raman spectroscopy. Spectroscopic results indicate that most of the adsorbed molecules are coordinated to either exchangeable cations (in the case of smectite group clays) or Lewis acidic centres (in the case of sepiolite and attapulgite) as bidentate ligands. The formation of monoanionic surface species has also been detected, to a relatively small extent. No physisorbed surface species has been observed. XRD patterns and UV-visible spectra of the samples are also recorded for additional information.

KW - FT-IR spectroscopy - FT-Raman spectroscopy - clays - sepiolite - attapulgite - hectorite - saponite - bentonite - adsorption - 2

KW - 2-bipyridyl

U2 - 10.1007/BF00705816

DO - 10.1007/BF00705816

M3 - Journal article

VL - 18

SP - 123

EP - 135

JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry

JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry

SN - 0923-0750

IS - 2

ER -