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Allene-derived gold and platinum complexes: synthesis and first applications in catalysis

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Allene-derived gold and platinum complexes: synthesis and first applications in catalysis. / Maliszewska, Hanna; Hughes, David; Munoz-Herranz, Maria Paz.
In: Dalton Transactions, Vol. 49, No. 13, 28.02.2020, p. 4034-4038.

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Maliszewska H, Hughes D, Munoz-Herranz MP. Allene-derived gold and platinum complexes: synthesis and first applications in catalysis. Dalton Transactions. 2020 Feb 28;49(13):4034-4038. doi: 10.1039/D0DT00665C

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@article{365559523eb845c4a9b145bb17b29ab3,
title = "Allene-derived gold and platinum complexes: synthesis and first applications in catalysis",
abstract = "We report here the synthesis, full characterisation and first application in catalysis of novel Au(I), Au(III) and Pt(II) carbene-type complexes formed from bis(pyridyl)allenes. The catalytic activity of the new Au(I)-complexes in the cylisation of 1,6-enynes, benchmark reaction for new Au and Pt complexes, was comparable to Au(I)-state-of-the-art catalysts used in these reactions. Reactions with the new Au(III)- and Pt(II)-complexes ocurred under milder conditions than the reported with AuCl3 and PtCl2.",
author = "Hanna Maliszewska and David Hughes and Munoz-Herranz, {Maria Paz}",
year = "2020",
month = feb,
day = "28",
doi = "10.1039/D0DT00665C",
language = "English",
volume = "49",
pages = "4034--4038",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "13",

}

RIS

TY - JOUR

T1 - Allene-derived gold and platinum complexes: synthesis and first applications in catalysis

AU - Maliszewska, Hanna

AU - Hughes, David

AU - Munoz-Herranz, Maria Paz

PY - 2020/2/28

Y1 - 2020/2/28

N2 - We report here the synthesis, full characterisation and first application in catalysis of novel Au(I), Au(III) and Pt(II) carbene-type complexes formed from bis(pyridyl)allenes. The catalytic activity of the new Au(I)-complexes in the cylisation of 1,6-enynes, benchmark reaction for new Au and Pt complexes, was comparable to Au(I)-state-of-the-art catalysts used in these reactions. Reactions with the new Au(III)- and Pt(II)-complexes ocurred under milder conditions than the reported with AuCl3 and PtCl2.

AB - We report here the synthesis, full characterisation and first application in catalysis of novel Au(I), Au(III) and Pt(II) carbene-type complexes formed from bis(pyridyl)allenes. The catalytic activity of the new Au(I)-complexes in the cylisation of 1,6-enynes, benchmark reaction for new Au and Pt complexes, was comparable to Au(I)-state-of-the-art catalysts used in these reactions. Reactions with the new Au(III)- and Pt(II)-complexes ocurred under milder conditions than the reported with AuCl3 and PtCl2.

U2 - 10.1039/D0DT00665C

DO - 10.1039/D0DT00665C

M3 - Journal article

VL - 49

SP - 4034

EP - 4038

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 13

ER -