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An alkyne hydrosilylation-Hiyama coupling approach to highly functionalised 1,3-dienes

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<mark>Journal publication date</mark>1/05/2015
<mark>Journal</mark>Organic Chemistry Frontiers
Issue number5
Volume2
Number of pages5
Pages (from-to)510-514
Publication StatusPublished
Early online date17/03/15
<mark>Original language</mark>English

Abstract

A high yielding and robust protocol for the stereodefined synthesis of 1,3-dienes has been established through a hydrosilylation–Hiyama coupling strategy. In all cases the products were formed as single E,E isomers and conditions are tolerant of a wide range of functional groups not compatible with other methods.