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An Operationally Simple, Regioselective, Platinum‐Catalyzed Hydroboration of Unactivated Alkynes

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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An Operationally Simple, Regioselective, Platinum‐Catalyzed Hydroboration of Unactivated Alkynes. / Hale, K. Lawrence E.; Roberts, Dean D.; McLaughlin, Mark Gerard.
In: European Journal of Organic Chemistry, Vol. 28, No. 11, e202401355, 17.03.2025.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Hale, KLE, Roberts, DD & McLaughlin, MG 2025, 'An Operationally Simple, Regioselective, Platinum‐Catalyzed Hydroboration of Unactivated Alkynes', European Journal of Organic Chemistry, vol. 28, no. 11, e202401355. https://doi.org/10.1002/ejoc.202401355

APA

Hale, K. L. E., Roberts, D. D., & McLaughlin, M. G. (2025). An Operationally Simple, Regioselective, Platinum‐Catalyzed Hydroboration of Unactivated Alkynes. European Journal of Organic Chemistry, 28(11), Article e202401355. https://doi.org/10.1002/ejoc.202401355

Vancouver

Hale KLE, Roberts DD, McLaughlin MG. An Operationally Simple, Regioselective, Platinum‐Catalyzed Hydroboration of Unactivated Alkynes. European Journal of Organic Chemistry. 2025 Mar 17;28(11):e202401355. Epub 2025 Feb 6. doi: 10.1002/ejoc.202401355

Author

Hale, K. Lawrence E. ; Roberts, Dean D. ; McLaughlin, Mark Gerard. / An Operationally Simple, Regioselective, Platinum‐Catalyzed Hydroboration of Unactivated Alkynes. In: European Journal of Organic Chemistry. 2025 ; Vol. 28, No. 11.

Bibtex

@article{ee416443b04246a9b5e915ba4bf9f3a6,
title = "An Operationally Simple, Regioselective, Platinum‐Catalyzed Hydroboration of Unactivated Alkynes",
abstract = "Herein is reported a new PtCl2/XPhos/Et3SiH‐catalyzed hydroboration method for unactivated terminal alkynes. Significantly, the reaction proceeds in hindered alkyne systems, and works well on acetylenes that contain multiple heteroatom‐groups to provide the desired (E)‐1,2‐vinyl boronates in reasonable to high yields with excellent levels of stereo‐ and regio‐control.",
author = "Hale, {K. Lawrence E.} and Roberts, {Dean D.} and McLaughlin, {Mark Gerard}",
year = "2025",
month = mar,
day = "17",
doi = "10.1002/ejoc.202401355",
language = "English",
volume = "28",
journal = "European Journal of Organic Chemistry",
issn = "1434-193X",
publisher = "Wiley-VCH Verlag",
number = "11",

}

RIS

TY - JOUR

T1 - An Operationally Simple, Regioselective, Platinum‐Catalyzed Hydroboration of Unactivated Alkynes

AU - Hale, K. Lawrence E.

AU - Roberts, Dean D.

AU - McLaughlin, Mark Gerard

PY - 2025/3/17

Y1 - 2025/3/17

N2 - Herein is reported a new PtCl2/XPhos/Et3SiH‐catalyzed hydroboration method for unactivated terminal alkynes. Significantly, the reaction proceeds in hindered alkyne systems, and works well on acetylenes that contain multiple heteroatom‐groups to provide the desired (E)‐1,2‐vinyl boronates in reasonable to high yields with excellent levels of stereo‐ and regio‐control.

AB - Herein is reported a new PtCl2/XPhos/Et3SiH‐catalyzed hydroboration method for unactivated terminal alkynes. Significantly, the reaction proceeds in hindered alkyne systems, and works well on acetylenes that contain multiple heteroatom‐groups to provide the desired (E)‐1,2‐vinyl boronates in reasonable to high yields with excellent levels of stereo‐ and regio‐control.

U2 - 10.1002/ejoc.202401355

DO - 10.1002/ejoc.202401355

M3 - Journal article

VL - 28

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

SN - 1434-193X

IS - 11

M1 - e202401355

ER -