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Asymmetric crystal growth of alpha-resorcinol from the vapor phase: surface reconstruction and conformational change are the culprits

Research output: Contribution to Journal/MagazineJournal articlepeer-review

<mark>Journal publication date</mark>2007
<mark>Journal</mark>Angewandte Chemie International Edition
Issue number29
Number of pages4
Pages (from-to)5537-5540
Publication StatusPublished
<mark>Original language</mark>English


Differential growth: The growth of crystals of α-resorcinol (see picture; C gray, H white, O red) from the vapor phase is asymmetric along the polar axis. By means of molecular-dynamics simulations, the slower growth at the (011) polar surface is traced back to conformational change of the molecule and to surface reconstruction, which may be a general phenomenon in polar crystals.