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Atmospheric mixing ratios of methyl ethyl ketone (2-butanone) in tropical, boreal, temperate and marine environments

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Atmospheric mixing ratios of methyl ethyl ketone (2-butanone) in tropical, boreal, temperate and marine environments. / Yañez-Serrano, Ana-Maria; Hewitt, C. N.

In: Atmospheric Chemistry and Physics , Vol. 16, No. 17, 06.09.2016, p. 10965-10984.

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Yañez-Serrano, Ana-Maria ; Hewitt, C. N. / Atmospheric mixing ratios of methyl ethyl ketone (2-butanone) in tropical, boreal, temperate and marine environments. In: Atmospheric Chemistry and Physics . 2016 ; Vol. 16, No. 17. pp. 10965-10984.

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@article{c10924d9cbfd4ba7ba6733f4a07d4c4d,
title = "Atmospheric mixing ratios of methyl ethyl ketone (2-butanone) in tropical, boreal, temperate and marine environments",
abstract = "Methyl ethyl ketone (MEK) enters the atmosphere following direct emission from vegetation and anthropogenic activities, as well as being produced by the gas-phase oxidation of volatile organic compounds (VOCs) such as n-butane. This study presents the first overview of ambient MEK measurements at six different locations, characteristic of forested, urban and marine environments. In order to understand better the occurrence and behaviour of MEK in the atmosphere, we analyse diel cycles of MEK mixing ratios, vertical profiles, ecosystem flux data, and HYSPLIT back trajectories, and compare with co-measured VOCs. MEK measurements were primarily conducted with proton transfer reaction–mass spectrometer (PTR-MS) instruments. Results from the sites under biogenic influence demonstrate that vegetation is an important source of MEK. The diel cycle of MEK follows that of ambient temperature and the forest structure plays an important role in air mixing. At such sites a high correlation of MEK with acetone was observed (e.g. r2 = 0.96 for the SMEAR-Estonia site in a remote hemi-boreal forest in Tartumaa, Estonia, and r2 = 0.89 at the ATTO pristine tropical rainforest site in central Amazonia). Under polluted conditions, we observed strongly enhanced MEK mixing ratios. Overall, the MEK mixing ratios and flux data presented here indicate that both biogenic and anthropogenic sources contribute to its occurrence in the global atmosphere.",
author = "Ana-Maria Ya{\~n}ez-Serrano and Hewitt, {C. N.}",
year = "2016",
month = sep,
day = "6",
doi = "10.5194/acp-2016-317",
language = "English",
volume = "16",
pages = "10965--10984",
journal = "Atmospheric Chemistry and Physics ",
issn = "1680-7316",
publisher = "Copernicus GmbH (Copernicus Publications) on behalf of the European Geosciences Union (EGU)",
number = "17",

}

RIS

TY - JOUR

T1 - Atmospheric mixing ratios of methyl ethyl ketone (2-butanone) in tropical, boreal, temperate and marine environments

AU - Yañez-Serrano, Ana-Maria

AU - Hewitt, C. N.

PY - 2016/9/6

Y1 - 2016/9/6

N2 - Methyl ethyl ketone (MEK) enters the atmosphere following direct emission from vegetation and anthropogenic activities, as well as being produced by the gas-phase oxidation of volatile organic compounds (VOCs) such as n-butane. This study presents the first overview of ambient MEK measurements at six different locations, characteristic of forested, urban and marine environments. In order to understand better the occurrence and behaviour of MEK in the atmosphere, we analyse diel cycles of MEK mixing ratios, vertical profiles, ecosystem flux data, and HYSPLIT back trajectories, and compare with co-measured VOCs. MEK measurements were primarily conducted with proton transfer reaction–mass spectrometer (PTR-MS) instruments. Results from the sites under biogenic influence demonstrate that vegetation is an important source of MEK. The diel cycle of MEK follows that of ambient temperature and the forest structure plays an important role in air mixing. At such sites a high correlation of MEK with acetone was observed (e.g. r2 = 0.96 for the SMEAR-Estonia site in a remote hemi-boreal forest in Tartumaa, Estonia, and r2 = 0.89 at the ATTO pristine tropical rainforest site in central Amazonia). Under polluted conditions, we observed strongly enhanced MEK mixing ratios. Overall, the MEK mixing ratios and flux data presented here indicate that both biogenic and anthropogenic sources contribute to its occurrence in the global atmosphere.

AB - Methyl ethyl ketone (MEK) enters the atmosphere following direct emission from vegetation and anthropogenic activities, as well as being produced by the gas-phase oxidation of volatile organic compounds (VOCs) such as n-butane. This study presents the first overview of ambient MEK measurements at six different locations, characteristic of forested, urban and marine environments. In order to understand better the occurrence and behaviour of MEK in the atmosphere, we analyse diel cycles of MEK mixing ratios, vertical profiles, ecosystem flux data, and HYSPLIT back trajectories, and compare with co-measured VOCs. MEK measurements were primarily conducted with proton transfer reaction–mass spectrometer (PTR-MS) instruments. Results from the sites under biogenic influence demonstrate that vegetation is an important source of MEK. The diel cycle of MEK follows that of ambient temperature and the forest structure plays an important role in air mixing. At such sites a high correlation of MEK with acetone was observed (e.g. r2 = 0.96 for the SMEAR-Estonia site in a remote hemi-boreal forest in Tartumaa, Estonia, and r2 = 0.89 at the ATTO pristine tropical rainforest site in central Amazonia). Under polluted conditions, we observed strongly enhanced MEK mixing ratios. Overall, the MEK mixing ratios and flux data presented here indicate that both biogenic and anthropogenic sources contribute to its occurrence in the global atmosphere.

U2 - 10.5194/acp-2016-317

DO - 10.5194/acp-2016-317

M3 - Journal article

VL - 16

SP - 10965

EP - 10984

JO - Atmospheric Chemistry and Physics

JF - Atmospheric Chemistry and Physics

SN - 1680-7316

IS - 17

ER -