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Azo-functionalised metal–organic framework for charge storage in sodium-ion batteries †

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Azo-functionalised metal–organic framework for charge storage in sodium-ion batteries †. / Desai, Aamod V.; Seymour, Valerie R.; Ettlinger, Romy et al.
In: Chemical Communications, Vol. 59, No. 10, 04.02.2023, p. 1321-1324.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Desai, AV, Seymour, VR, Ettlinger, R, Pramanik, A, Manche, AG, Rainer, DN, Wheatley, PS, Griffin, JM, Morris, RE & Armstrong, AR 2023, 'Azo-functionalised metal–organic framework for charge storage in sodium-ion batteries †', Chemical Communications, vol. 59, no. 10, pp. 1321-1324. https://doi.org/10.1039/d2cc06154f

APA

Desai, A. V., Seymour, V. R., Ettlinger, R., Pramanik, A., Manche, A. G., Rainer, D. N., Wheatley, P. S., Griffin, J. M., Morris, R. E., & Armstrong, A. R. (2023). Azo-functionalised metal–organic framework for charge storage in sodium-ion batteries †. Chemical Communications, 59(10), 1321-1324. https://doi.org/10.1039/d2cc06154f

Vancouver

Desai AV, Seymour VR, Ettlinger R, Pramanik A, Manche AG, Rainer DN et al. Azo-functionalised metal–organic framework for charge storage in sodium-ion batteries †. Chemical Communications. 2023 Feb 4;59(10):1321-1324. Epub 2022 Dec 30. doi: 10.1039/d2cc06154f

Author

Desai, Aamod V. ; Seymour, Valerie R. ; Ettlinger, Romy et al. / Azo-functionalised metal–organic framework for charge storage in sodium-ion batteries †. In: Chemical Communications. 2023 ; Vol. 59, No. 10. pp. 1321-1324.

Bibtex

@article{3e558523fdd94b92bf494b1480c0600d,
title = "Azo-functionalised metal–organic framework for charge storage in sodium-ion batteries †",
abstract = "Sodium-ion batteries (NIBs) are emerging as promising devices for energy storage applications. Porous solids, such as metal–organic frameworks (MOFs), are well suited as electrode materials for technologies involving bulkier charge carriers. However, only limited progress has been made using pristine MOFs, primarily due to lack of redox-active organic groups in the materials. In this work a azo-functional MOF, namely UiO-abdc, is presented as an electrode compound for sodium-ion insertion. The MOF delivers a stable capacity (∼100 mA h g−1) over 150 cycles, and post-cycling characterisation validates the stability of the MOF and participation of the azo-group in charge storage. This study can accelerate the realisation of pristine solids, such as MOFs and other porous organic compounds, as battery materials.",
author = "Desai, {Aamod V.} and Seymour, {Valerie R.} and Romy Ettlinger and Atin Pramanik and Manche, {Alexis G.} and Rainer, {Daniel N.} and Wheatley, {Paul S.} and Griffin, {John M.} and Morris, {Russell E.} and Armstrong, {A. Robert}",
year = "2023",
month = feb,
day = "4",
doi = "10.1039/d2cc06154f",
language = "English",
volume = "59",
pages = "1321--1324",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "10",

}

RIS

TY - JOUR

T1 - Azo-functionalised metal–organic framework for charge storage in sodium-ion batteries †

AU - Desai, Aamod V.

AU - Seymour, Valerie R.

AU - Ettlinger, Romy

AU - Pramanik, Atin

AU - Manche, Alexis G.

AU - Rainer, Daniel N.

AU - Wheatley, Paul S.

AU - Griffin, John M.

AU - Morris, Russell E.

AU - Armstrong, A. Robert

PY - 2023/2/4

Y1 - 2023/2/4

N2 - Sodium-ion batteries (NIBs) are emerging as promising devices for energy storage applications. Porous solids, such as metal–organic frameworks (MOFs), are well suited as electrode materials for technologies involving bulkier charge carriers. However, only limited progress has been made using pristine MOFs, primarily due to lack of redox-active organic groups in the materials. In this work a azo-functional MOF, namely UiO-abdc, is presented as an electrode compound for sodium-ion insertion. The MOF delivers a stable capacity (∼100 mA h g−1) over 150 cycles, and post-cycling characterisation validates the stability of the MOF and participation of the azo-group in charge storage. This study can accelerate the realisation of pristine solids, such as MOFs and other porous organic compounds, as battery materials.

AB - Sodium-ion batteries (NIBs) are emerging as promising devices for energy storage applications. Porous solids, such as metal–organic frameworks (MOFs), are well suited as electrode materials for technologies involving bulkier charge carriers. However, only limited progress has been made using pristine MOFs, primarily due to lack of redox-active organic groups in the materials. In this work a azo-functional MOF, namely UiO-abdc, is presented as an electrode compound for sodium-ion insertion. The MOF delivers a stable capacity (∼100 mA h g−1) over 150 cycles, and post-cycling characterisation validates the stability of the MOF and participation of the azo-group in charge storage. This study can accelerate the realisation of pristine solids, such as MOFs and other porous organic compounds, as battery materials.

U2 - 10.1039/d2cc06154f

DO - 10.1039/d2cc06154f

M3 - Journal article

VL - 59

SP - 1321

EP - 1324

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 10

ER -