Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
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TY - JOUR
T1 - Band gap engineering in fluorescent conjugated microporous polymers
AU - Jiang, Jia-Xing
AU - Trewin, Abbie
AU - Adams, Dave J.
AU - Cooper, Andrew I.
PY - 2011/9/1
Y1 - 2011/9/1
N2 - We report here the synthesis of conjugated microporous polymers (CMPs) based on pyrene building units. The networks are both microporous and highly luminescent. The emission colour and resulting band gap can be fine tuned by introducing different comonomers and by varying the monomer distribution (statistical versus alternating). These materials might find applications in organic electronics, photocatalysis, optoelectronics, or in sensing technologies.
AB - We report here the synthesis of conjugated microporous polymers (CMPs) based on pyrene building units. The networks are both microporous and highly luminescent. The emission colour and resulting band gap can be fine tuned by introducing different comonomers and by varying the monomer distribution (statistical versus alternating). These materials might find applications in organic electronics, photocatalysis, optoelectronics, or in sensing technologies.
KW - HIGH-SURFACE-AREA
KW - INTRINSIC MICROPOROSITY
KW - ORGANIC FRAMEWORK
KW - HYDROGEN STORAGE
KW - NETWORKS
KW - POLYMERIZATION
KW - LUMINESCENT
KW - PYRENE
KW - POLYFLUORENES
KW - CRYSTALLINE
U2 - 10.1039/c1sc00329a
DO - 10.1039/c1sc00329a
M3 - Journal article
VL - 2
SP - 1777
EP - 1781
JO - Chemical Science
JF - Chemical Science
SN - 2041-6520
IS - 9
ER -