Research output: Contribution to Journal/Magazine › Literature review › peer-review
Research output: Contribution to Journal/Magazine › Literature review › peer-review
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TY - JOUR
T1 - Biocompatible initiators for lactide polymerization
AU - Platel, Rachel H.
AU - Hodgson, Linda M.
AU - Williams, Charlotte K.
PY - 2008
Y1 - 2008
N2 - The review summarizes recent developments in the preparation and use of new initiators for the ring opening polymerization of lactide. The review compares different classes of initiator including metal complexes, classed according to their group in the periodic table, and carbon-based initiators/organocatalysts. Emphasis is placed on the polymerization kinetics and the control exhibited by the different types of initiators. Where useful properties, such as high rates or stereocontrol, have been observed a more detailed examination of the initiator is provided. A further focus of the review is initiators displaying low toxicity and biocompatibility.
AB - The review summarizes recent developments in the preparation and use of new initiators for the ring opening polymerization of lactide. The review compares different classes of initiator including metal complexes, classed according to their group in the periodic table, and carbon-based initiators/organocatalysts. Emphasis is placed on the polymerization kinetics and the control exhibited by the different types of initiators. Where useful properties, such as high rates or stereocontrol, have been observed a more detailed examination of the initiator is provided. A further focus of the review is initiators displaying low toxicity and biocompatibility.
KW - GROUP-3 METAL-COMPLEXES
KW - HIGHLY EFFICIENT CATALYST
KW - polyester
KW - ESTER-EXCHANGE-REACTIONS
KW - initiators
KW - SINGLE-SITE CATALYSTS
KW - ORGANOCATALYTIC LIVING POLYMERIZATION
KW - CHAIN-END CONTROL
KW - CYCLIC ESTERS
KW - N-HETEROCYCLIC CARBENES
KW - ring-opening polymerisation
KW - polylactide
KW - PLA/PEO/PLA TRIBLOCK COPOLYMERS
KW - RING-OPENING POLYMERIZATION
U2 - 10.1080/15583720701834166
DO - 10.1080/15583720701834166
M3 - Literature review
VL - 48
SP - 11
EP - 63
JO - Polymer Reviews
JF - Polymer Reviews
SN - 1558-3724
IS - 1
ER -