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Chiral Co<sub>3</sub>Y Propeller-Shaped Chemosensory Platforms Based on <sup>19</sup>F-NMR

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Chiral Co<sub>3</sub>Y Propeller-Shaped Chemosensory Platforms Based on <sup>19</sup>F-NMR. / Audsley, Gabrielle; Carpenter, Harry; Essien, Nsikak B. et al.
In: Inorganic Chemistry, Vol. 62, No. 6, 13.02.2023, p. 2680-2693.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Audsley, G, Carpenter, H, Essien, NB, Lai-Morrice, J, Al-Hilaly, Y, Serpell, LC, Akien, GR, Tizzard, GJ, Coles, SJ, Ulldemolins, CP & Kostakis, GE 2023, 'Chiral Co<sub>3</sub>Y Propeller-Shaped Chemosensory Platforms Based on <sup>19</sup>F-NMR', Inorganic Chemistry, vol. 62, no. 6, pp. 2680-2693. https://doi.org/10.1021/acs.inorgchem.2c03737

APA

Audsley, G., Carpenter, H., Essien, N. B., Lai-Morrice, J., Al-Hilaly, Y., Serpell, L. C., Akien, G. R., Tizzard, G. J., Coles, S. J., Ulldemolins, C. P., & Kostakis, G. E. (2023). Chiral Co<sub>3</sub>Y Propeller-Shaped Chemosensory Platforms Based on <sup>19</sup>F-NMR. Inorganic Chemistry, 62(6), 2680-2693. https://doi.org/10.1021/acs.inorgchem.2c03737

Vancouver

Audsley G, Carpenter H, Essien NB, Lai-Morrice J, Al-Hilaly Y, Serpell LC et al. Chiral Co<sub>3</sub>Y Propeller-Shaped Chemosensory Platforms Based on <sup>19</sup>F-NMR. Inorganic Chemistry. 2023 Feb 13;62(6):2680-2693. Epub 2023 Jan 30. doi: 10.1021/acs.inorgchem.2c03737

Author

Audsley, Gabrielle ; Carpenter, Harry ; Essien, Nsikak B. et al. / Chiral Co<sub>3</sub>Y Propeller-Shaped Chemosensory Platforms Based on <sup>19</sup>F-NMR. In: Inorganic Chemistry. 2023 ; Vol. 62, No. 6. pp. 2680-2693.

Bibtex

@article{837dc03c0c83403cad3a85abd1196697,
title = "Chiral Co3Y Propeller-Shaped Chemosensory Platforms Based on 19F-NMR",
abstract = "Two propeller-shaped chiral CoIII3YIII complexes built from fluorinated ligands are synthesized and characterized by single-crystal X-ray diffraction (SXRD), IR, UV–vis, circular dichroism (CD), elemental analysis, thermogravimetric analysis (TGA), electron spray ionization mass spectroscopy (ESI-MS), and NMR (1H, 13C, and 19F). This work explores the sensing and discrimination abilities of these complexes, thus providing an innovative sensing method using a 19F NMR chemosensory system and opening new directions in 3d/4f chemistry. Control experiments and theoretical studies shed light on the sensing mechanism, while the scope and limitations of this method are discussed and presented.",
keywords = "Inorganic Chemistry, Physical and Theoretical Chemistry",
author = "Gabrielle Audsley and Harry Carpenter and Essien, {Nsikak B.} and James Lai-Morrice and Youssra Al-Hilaly and Serpell, {Louise C.} and Akien, {Geoffrey R.} and Tizzard, {Graham J.} and Coles, {Simon J.} and Ulldemolins, {Cristina Pubill} and Kostakis, {George E.}",
year = "2023",
month = feb,
day = "13",
doi = "10.1021/acs.inorgchem.2c03737",
language = "English",
volume = "62",
pages = "2680--2693",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "6",

}

RIS

TY - JOUR

T1 - Chiral Co3Y Propeller-Shaped Chemosensory Platforms Based on 19F-NMR

AU - Audsley, Gabrielle

AU - Carpenter, Harry

AU - Essien, Nsikak B.

AU - Lai-Morrice, James

AU - Al-Hilaly, Youssra

AU - Serpell, Louise C.

AU - Akien, Geoffrey R.

AU - Tizzard, Graham J.

AU - Coles, Simon J.

AU - Ulldemolins, Cristina Pubill

AU - Kostakis, George E.

PY - 2023/2/13

Y1 - 2023/2/13

N2 - Two propeller-shaped chiral CoIII3YIII complexes built from fluorinated ligands are synthesized and characterized by single-crystal X-ray diffraction (SXRD), IR, UV–vis, circular dichroism (CD), elemental analysis, thermogravimetric analysis (TGA), electron spray ionization mass spectroscopy (ESI-MS), and NMR (1H, 13C, and 19F). This work explores the sensing and discrimination abilities of these complexes, thus providing an innovative sensing method using a 19F NMR chemosensory system and opening new directions in 3d/4f chemistry. Control experiments and theoretical studies shed light on the sensing mechanism, while the scope and limitations of this method are discussed and presented.

AB - Two propeller-shaped chiral CoIII3YIII complexes built from fluorinated ligands are synthesized and characterized by single-crystal X-ray diffraction (SXRD), IR, UV–vis, circular dichroism (CD), elemental analysis, thermogravimetric analysis (TGA), electron spray ionization mass spectroscopy (ESI-MS), and NMR (1H, 13C, and 19F). This work explores the sensing and discrimination abilities of these complexes, thus providing an innovative sensing method using a 19F NMR chemosensory system and opening new directions in 3d/4f chemistry. Control experiments and theoretical studies shed light on the sensing mechanism, while the scope and limitations of this method are discussed and presented.

KW - Inorganic Chemistry

KW - Physical and Theoretical Chemistry

U2 - 10.1021/acs.inorgchem.2c03737

DO - 10.1021/acs.inorgchem.2c03737

M3 - Journal article

C2 - 36716401

VL - 62

SP - 2680

EP - 2693

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 6

ER -