Home > Research > Publications & Outputs > Clathrate and inclusion compounds: part 14 : va...

Research

Links

Text available via DOI:

View graph of relations

Clathrate and inclusion compounds: part 14 : variable temperature vibrational spectroscopic studies of monosubstituted cyclohexane guests in thiourea.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Published

Standard

Clathrate and inclusion compounds: part 14 : variable temperature vibrational spectroscopic studies of monosubstituted cyclohexane guests in thiourea. / Davies, J. Eric D.; Nightingale, G. J.
In: Journal of Structural Chemistry, Vol. 40, No. 5, 09.1999, p. 802-805.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Davies, JED & Nightingale, GJ 1999, 'Clathrate and inclusion compounds: part 14 : variable temperature vibrational spectroscopic studies of monosubstituted cyclohexane guests in thiourea.', Journal of Structural Chemistry, vol. 40, no. 5, pp. 802-805. https://doi.org/10.1007/BF02903456

APA

Davies, J. E. D., & Nightingale, G. J. (1999). Clathrate and inclusion compounds: part 14 : variable temperature vibrational spectroscopic studies of monosubstituted cyclohexane guests in thiourea. Journal of Structural Chemistry, 40(5), 802-805. https://doi.org/10.1007/BF02903456

Vancouver

Davies JED, Nightingale GJ. Clathrate and inclusion compounds: part 14 : variable temperature vibrational spectroscopic studies of monosubstituted cyclohexane guests in thiourea. Journal of Structural Chemistry. 1999 Sept;40(5):802-805. doi: 10.1007/BF02903456

Author

Davies, J. Eric D. ; Nightingale, G. J. / Clathrate and inclusion compounds: part 14 : variable temperature vibrational spectroscopic studies of monosubstituted cyclohexane guests in thiourea. In: Journal of Structural Chemistry. 1999 ; Vol. 40, No. 5. pp. 802-805.

Bibtex

@article{2a125f7755014494b6ec55df73f2e5c0,
title = "Clathrate and inclusion compounds: part 14 : variable temperature vibrational spectroscopic studies of monosubstituted cyclohexane guests in thiourea.",
abstract = "Infrared and Raman spectra over the temperature range room temperature to 74K have been recorded for a range of inclusion compounds of thiourea containing monosubstituted cyclohexanes C6H11X (X =Cl,Br,I,CN,NCO) as guests. The liquid phase of all the cyclohexanes consists of an equilibrium mixture of axial and equatorial conformers, with the equatorial conformer being the more abundant. At room temperature the chloro, bromo and cyano substituted guests exist predominantly as the axial conformer, whereas the iodo and isocyanato substituted guests exist as a mixture of both conformers, but with the axial conformer being the more abundant. The iodocyclohexane inclusion compound was the only one to display a temperature dependent change in the intensity ratio of the conformer bands. This could be due to a change in the conformer ratio or to a structural phase change.",
author = "Davies, {J. Eric D.} and Nightingale, {G. J.}",
year = "1999",
month = sep,
doi = "10.1007/BF02903456",
language = "English",
volume = "40",
pages = "802--805",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "5",

}

RIS

TY - JOUR

T1 - Clathrate and inclusion compounds: part 14 : variable temperature vibrational spectroscopic studies of monosubstituted cyclohexane guests in thiourea.

AU - Davies, J. Eric D.

AU - Nightingale, G. J.

PY - 1999/9

Y1 - 1999/9

N2 - Infrared and Raman spectra over the temperature range room temperature to 74K have been recorded for a range of inclusion compounds of thiourea containing monosubstituted cyclohexanes C6H11X (X =Cl,Br,I,CN,NCO) as guests. The liquid phase of all the cyclohexanes consists of an equilibrium mixture of axial and equatorial conformers, with the equatorial conformer being the more abundant. At room temperature the chloro, bromo and cyano substituted guests exist predominantly as the axial conformer, whereas the iodo and isocyanato substituted guests exist as a mixture of both conformers, but with the axial conformer being the more abundant. The iodocyclohexane inclusion compound was the only one to display a temperature dependent change in the intensity ratio of the conformer bands. This could be due to a change in the conformer ratio or to a structural phase change.

AB - Infrared and Raman spectra over the temperature range room temperature to 74K have been recorded for a range of inclusion compounds of thiourea containing monosubstituted cyclohexanes C6H11X (X =Cl,Br,I,CN,NCO) as guests. The liquid phase of all the cyclohexanes consists of an equilibrium mixture of axial and equatorial conformers, with the equatorial conformer being the more abundant. At room temperature the chloro, bromo and cyano substituted guests exist predominantly as the axial conformer, whereas the iodo and isocyanato substituted guests exist as a mixture of both conformers, but with the axial conformer being the more abundant. The iodocyclohexane inclusion compound was the only one to display a temperature dependent change in the intensity ratio of the conformer bands. This could be due to a change in the conformer ratio or to a structural phase change.

U2 - 10.1007/BF02903456

DO - 10.1007/BF02903456

M3 - Journal article

VL - 40

SP - 802

EP - 805

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 5

ER -