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Cobalt-based molecular electrocatalysis of nitrile reduction: evolving sustainability beyond hydrogen

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Cobalt-based molecular electrocatalysis of nitrile reduction: evolving sustainability beyond hydrogen. / Child, Simon; Raychev, Radoslav; Moss, Nathan et al.
In: Dalton Transactions, Vol. 48, No. 26, 14.07.2019, p. 9576-9580.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Child, S, Raychev, R, Moss, N, Howchen, B, Horton, PN, Prior, C, Oganesyan, V & Fielden, J 2019, 'Cobalt-based molecular electrocatalysis of nitrile reduction: evolving sustainability beyond hydrogen', Dalton Transactions, vol. 48, no. 26, pp. 9576-9580. https://doi.org/10.1039/c9dt00773c

APA

Child, S., Raychev, R., Moss, N., Howchen, B., Horton, P. N., Prior, C., Oganesyan, V., & Fielden, J. (2019). Cobalt-based molecular electrocatalysis of nitrile reduction: evolving sustainability beyond hydrogen. Dalton Transactions, 48(26), 9576-9580. https://doi.org/10.1039/c9dt00773c

Vancouver

Child S, Raychev R, Moss N, Howchen B, Horton PN, Prior C et al. Cobalt-based molecular electrocatalysis of nitrile reduction: evolving sustainability beyond hydrogen. Dalton Transactions. 2019 Jul 14;48(26):9576-9580. doi: 10.1039/c9dt00773c

Author

Child, Simon ; Raychev, Radoslav ; Moss, Nathan et al. / Cobalt-based molecular electrocatalysis of nitrile reduction: evolving sustainability beyond hydrogen. In: Dalton Transactions. 2019 ; Vol. 48, No. 26. pp. 9576-9580.

Bibtex

@article{44dca039b14b4145b31df0f3093efb0d,
title = "Cobalt-based molecular electrocatalysis of nitrile reduction: evolving sustainability beyond hydrogen",
abstract = "Two new cobalt bis-iminopyridines, [Co(DDP)(H2O)2](NO3)2 (1, DDP = cis-[1,3-bis(2-pyridinylenamine)] cyclohexane) and [Co(cis-DDOP)(NO3)](NO3) (2, cis-DDOP = cis-3,5-bis[(2- Pyridinyleneamin]-trans-hydroxycyclohexane) electrocatalyse the 4-proton, 4-electron reduction of acetonitrile to ethylamine. For 1, this reduction occurs in preference to reduction of protons to H2. A coordinating hydroxyl proton relay in 2 reduces the yield of ethylamine and biases the catalytic system back towards H2.",
author = "Simon Child and Radoslav Raychev and Nathan Moss and Benjamin Howchen and Horton, {Peter N.} and Christopher Prior and Vasily Oganesyan and John Fielden",
year = "2019",
month = jul,
day = "14",
doi = "10.1039/c9dt00773c",
language = "English",
volume = "48",
pages = "9576--9580",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "26",

}

RIS

TY - JOUR

T1 - Cobalt-based molecular electrocatalysis of nitrile reduction: evolving sustainability beyond hydrogen

AU - Child, Simon

AU - Raychev, Radoslav

AU - Moss, Nathan

AU - Howchen, Benjamin

AU - Horton, Peter N.

AU - Prior, Christopher

AU - Oganesyan, Vasily

AU - Fielden, John

PY - 2019/7/14

Y1 - 2019/7/14

N2 - Two new cobalt bis-iminopyridines, [Co(DDP)(H2O)2](NO3)2 (1, DDP = cis-[1,3-bis(2-pyridinylenamine)] cyclohexane) and [Co(cis-DDOP)(NO3)](NO3) (2, cis-DDOP = cis-3,5-bis[(2- Pyridinyleneamin]-trans-hydroxycyclohexane) electrocatalyse the 4-proton, 4-electron reduction of acetonitrile to ethylamine. For 1, this reduction occurs in preference to reduction of protons to H2. A coordinating hydroxyl proton relay in 2 reduces the yield of ethylamine and biases the catalytic system back towards H2.

AB - Two new cobalt bis-iminopyridines, [Co(DDP)(H2O)2](NO3)2 (1, DDP = cis-[1,3-bis(2-pyridinylenamine)] cyclohexane) and [Co(cis-DDOP)(NO3)](NO3) (2, cis-DDOP = cis-3,5-bis[(2- Pyridinyleneamin]-trans-hydroxycyclohexane) electrocatalyse the 4-proton, 4-electron reduction of acetonitrile to ethylamine. For 1, this reduction occurs in preference to reduction of protons to H2. A coordinating hydroxyl proton relay in 2 reduces the yield of ethylamine and biases the catalytic system back towards H2.

U2 - 10.1039/c9dt00773c

DO - 10.1039/c9dt00773c

M3 - Journal article

VL - 48

SP - 9576

EP - 9580

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 26

ER -