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Cobalt(II/III), nickel(II) and copper(II) coordination clusters employing a monoanionic Schiff base ligand: Synthetic, topological and computational mechanistic aspects

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  • Edward Loukopoulos
  • Benjamin Berkoff
  • Kieran Griffiths
  • Victoria Keeble
  • Vassiliki N. Dokorou
  • Athanassios C. Tsipis
  • Albert Escuer
  • George E. Kostakis
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<mark>Journal publication date</mark>3/08/2015
<mark>Journal</mark>CrystEngComm
Issue number35
Volume17
Number of pages12
Pages (from-to)6753-6764
Publication StatusPublished
<mark>Original language</mark>English

Abstract

Nine mono-, di- and tetranuclear coordination clusters (M = CoII/III, NiII, CuII) using a monoanionic Schiff base ligand were synthesized and characterized by X-ray crystallography. A series of transformations occur in the ligand in certain compounds for which theoretical studies are presented. Synthetic aspects, topological issues and magnetic studies are discussed.