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    Rights statement: This is the author’s version of a work that was accepted for publication in Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 925, 2022 DOI: 10.1016/j.jelechem.2022.116884

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Comparative study for electrochemical and Single-Cell performance of a novel MXene-Supported Platinum–Ruthenium catalyst for Direct methanol fuel cell application

Research output: Contribution to Journal/Magazine › Journal article › peer-review

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Comparative study for electrochemical and Single-Cell performance of a novel MXene-Supported Platinum–Ruthenium catalyst for Direct methanol fuel cell application. / Abdullah, N.; Rahman, S.; Mohd Zainoodin, A. et al.
In: Journal of Electroanalytical Chemistry, Vol. 925, 116884, 15.11.2022.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Abdullah, N, Rahman, S, Mohd Zainoodin, A & Aslfattahi, N 2022, 'Comparative study for electrochemical and Single-Cell performance of a novel MXene-Supported Platinum–Ruthenium catalyst for Direct methanol fuel cell application', Journal of Electroanalytical Chemistry, vol. 925, 116884. https://doi.org/10.1016/j.jelechem.2022.116884

APA

Abdullah, N., Rahman, S., Mohd Zainoodin, A., & Aslfattahi, N. (2022). Comparative study for electrochemical and Single-Cell performance of a novel MXene-Supported Platinum–Ruthenium catalyst for Direct methanol fuel cell application. Journal of Electroanalytical Chemistry, 925, Article 116884. https://doi.org/10.1016/j.jelechem.2022.116884

Vancouver

Abdullah N, Rahman S, Mohd Zainoodin A, Aslfattahi N. Comparative study for electrochemical and Single-Cell performance of a novel MXene-Supported Platinum–Ruthenium catalyst for Direct methanol fuel cell application. Journal of Electroanalytical Chemistry. 2022 Nov 15;925:116884. Epub 2022 Oct 14. doi: 10.1016/j.jelechem.2022.116884

Author

Abdullah, N. ; Rahman, S. ; Mohd Zainoodin, A. et al. / Comparative study for electrochemical and Single-Cell performance of a novel MXene-Supported Platinum–Ruthenium catalyst for Direct methanol fuel cell application. In: Journal of Electroanalytical Chemistry. 2022 ; Vol. 925.

Bibtex

@article{42ce1930dbca4083b2f13a60740bd72c,
title = "Comparative study for electrochemical and Single-Cell performance of a novel MXene-Supported Platinum–Ruthenium catalyst for Direct methanol fuel cell application",
abstract = "Direct methanol fuel cell (DMFC) is one of the reliable sources of energy owing to numerous benefits it offers and its suitability for portable electronic applications. Therefore, this study aims to overcome the main issues confronting anodic electrocatalyst part by introducing the novel formulation of platinum–ruthenium (PtRu) bimetal into the 2D Ti3C2Tx structure to boost the electrocatalytic activity and single-cell performance. A comparative study for electrochemical measurement and DMFC performance is conducted between as-synthesized electrocatalyst PtRu/Ti3C2Tx and two other electrocatalysts, PtRu/C and Pt/C. This comparative study between electrocatalyst revealed that PtRu/Ti3C2Tx exhibits the highest electrochemical surface area (55 m2 g-1), electrocatalytic and intrinsic activity (449 mA mgPtRu−1/ 1.36 mA cmECSA−2), carbon monoxide tolerance (1.56), and smallest charge-transfer resistance (2.66 Ω) compared with other electrocatalysts. Furthermore, the validation by DMFC single-cell test showed that PtRu/Ti3C2Tx electrocatalyst improves the performance almost 70 % compared to the Pt/C electrocatalyst. This excellent electrochemical and single-cell performance of PtRu/Ti3C2Tx electrocatalyst validates its potential to be one of the promising candidates for the anodic electrocatalyst in DMFC application.",
keywords = "Anodic electrocatalyst, Direct methanol fuel cell, Electrochemical measurement, MXene, Single cell performance",
author = "N. Abdullah and S. Rahman and {Mohd Zainoodin}, A. and N. Aslfattahi",
note = "This is the author{\textquoteright}s version of a work that was accepted for publication in Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 925, 2022 DOI: 10.1016/j.jelechem.2022.116884",
year = "2022",
month = nov,
day = "15",
doi = "10.1016/j.jelechem.2022.116884",
language = "English",
volume = "925",
journal = "Journal of Electroanalytical Chemistry",
issn = "0022-0728",

}

RIS

TY - JOUR

T1 - Comparative study for electrochemical and Single-Cell performance of a novel MXene-Supported Platinum–Ruthenium catalyst for Direct methanol fuel cell application

AU - Abdullah, N.

AU - Rahman, S.

AU - Mohd Zainoodin, A.

AU - Aslfattahi, N.

N1 - This is the author’s version of a work that was accepted for publication in Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 925, 2022 DOI: 10.1016/j.jelechem.2022.116884

PY - 2022/11/15

Y1 - 2022/11/15

N2 - Direct methanol fuel cell (DMFC) is one of the reliable sources of energy owing to numerous benefits it offers and its suitability for portable electronic applications. Therefore, this study aims to overcome the main issues confronting anodic electrocatalyst part by introducing the novel formulation of platinum–ruthenium (PtRu) bimetal into the 2D Ti3C2Tx structure to boost the electrocatalytic activity and single-cell performance. A comparative study for electrochemical measurement and DMFC performance is conducted between as-synthesized electrocatalyst PtRu/Ti3C2Tx and two other electrocatalysts, PtRu/C and Pt/C. This comparative study between electrocatalyst revealed that PtRu/Ti3C2Tx exhibits the highest electrochemical surface area (55 m2 g-1), electrocatalytic and intrinsic activity (449 mA mgPtRu−1/ 1.36 mA cmECSA−2), carbon monoxide tolerance (1.56), and smallest charge-transfer resistance (2.66 Ω) compared with other electrocatalysts. Furthermore, the validation by DMFC single-cell test showed that PtRu/Ti3C2Tx electrocatalyst improves the performance almost 70 % compared to the Pt/C electrocatalyst. This excellent electrochemical and single-cell performance of PtRu/Ti3C2Tx electrocatalyst validates its potential to be one of the promising candidates for the anodic electrocatalyst in DMFC application.

AB - Direct methanol fuel cell (DMFC) is one of the reliable sources of energy owing to numerous benefits it offers and its suitability for portable electronic applications. Therefore, this study aims to overcome the main issues confronting anodic electrocatalyst part by introducing the novel formulation of platinum–ruthenium (PtRu) bimetal into the 2D Ti3C2Tx structure to boost the electrocatalytic activity and single-cell performance. A comparative study for electrochemical measurement and DMFC performance is conducted between as-synthesized electrocatalyst PtRu/Ti3C2Tx and two other electrocatalysts, PtRu/C and Pt/C. This comparative study between electrocatalyst revealed that PtRu/Ti3C2Tx exhibits the highest electrochemical surface area (55 m2 g-1), electrocatalytic and intrinsic activity (449 mA mgPtRu−1/ 1.36 mA cmECSA−2), carbon monoxide tolerance (1.56), and smallest charge-transfer resistance (2.66 Ω) compared with other electrocatalysts. Furthermore, the validation by DMFC single-cell test showed that PtRu/Ti3C2Tx electrocatalyst improves the performance almost 70 % compared to the Pt/C electrocatalyst. This excellent electrochemical and single-cell performance of PtRu/Ti3C2Tx electrocatalyst validates its potential to be one of the promising candidates for the anodic electrocatalyst in DMFC application.

KW - Anodic electrocatalyst

KW - Direct methanol fuel cell

KW - Electrochemical measurement

KW - MXene

KW - Single cell performance

U2 - 10.1016/j.jelechem.2022.116884

DO - 10.1016/j.jelechem.2022.116884

M3 - Journal article

VL - 925

JO - Journal of Electroanalytical Chemistry

JF - Journal of Electroanalytical Chemistry

SN - 0022-0728

M1 - 116884

ER -