Comparison of ullmann/RCM and ullmann/bis-hydrazone coupling reactions; New access to benzodithiophenes for dye-sensitized solar cell and thiahelicene applications

Chemistry

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https://doi.org/10.1055/s-0033-1340667
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Keywords

alkene metathesis, benzodithiophene, bis-hydrazone coupling, Liebeskind's catalyst, non-photochemical synthesis

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Comparison of ullmann/RCM and ullmann/bis-hydrazone coupling reactions; New access to benzodithiophenes for dye-sensitized solar cell and thiahelicene applications. / Stephenson, G. Richard; Cauteruccio, Silvia; Doulcet, Julien.
In: SYNLETT, Vol. 25, No. 5, ST-2013-D0987-L, 05.02.2014, p. 701-707.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Bibtex

@article{f44ef4bcf70f498588e1f97343fd33dc,

title = "Comparison of ullmann/RCM and ullmann/bis-hydrazone coupling reactions; New access to benzodithiophenes for dye-sensitized solar cell and thiahelicene applications",

abstract = "The use of CuTC (Liebeskind's catalyst), followed by methylenation and ring-closing metathesis, or bis-hydrazone coupling reactions is described. This approach establishes an alternative non-photochemical synthesis of the strategically important 1,2-b:4,3-b′ BDT regioisomer, which has previously been underused in applications such as dye-sensitized solar cells and nonlinear optics because of the difficulty of synthesis on a large scale.",

keywords = "alkene metathesis, benzodithiophene, bis-hydrazone coupling, Liebeskind's catalyst, non-photochemical synthesis",

author = "Stephenson, {G. Richard} and Silvia Cauteruccio and Julien Doulcet",

year = "2014",

month = feb,

day = "5",

doi = "10.1055/s-0033-1340667",

language = "English",

volume = "25",

pages = "701--707",

journal = "SYNLETT",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "5",

}

RIS

TY - JOUR

T1 - Comparison of ullmann/RCM and ullmann/bis-hydrazone coupling reactions; New access to benzodithiophenes for dye-sensitized solar cell and thiahelicene applications

AU - Stephenson, G. Richard

AU - Cauteruccio, Silvia

AU - Doulcet, Julien

PY - 2014/2/5

Y1 - 2014/2/5

N2 - The use of CuTC (Liebeskind's catalyst), followed by methylenation and ring-closing metathesis, or bis-hydrazone coupling reactions is described. This approach establishes an alternative non-photochemical synthesis of the strategically important 1,2-b:4,3-b′ BDT regioisomer, which has previously been underused in applications such as dye-sensitized solar cells and nonlinear optics because of the difficulty of synthesis on a large scale.

AB - The use of CuTC (Liebeskind's catalyst), followed by methylenation and ring-closing metathesis, or bis-hydrazone coupling reactions is described. This approach establishes an alternative non-photochemical synthesis of the strategically important 1,2-b:4,3-b′ BDT regioisomer, which has previously been underused in applications such as dye-sensitized solar cells and nonlinear optics because of the difficulty of synthesis on a large scale.

KW - alkene metathesis

KW - benzodithiophene

KW - bis-hydrazone coupling

KW - Liebeskind's catalyst

KW - non-photochemical synthesis

U2 - 10.1055/s-0033-1340667

DO - 10.1055/s-0033-1340667

M3 - Journal article

AN - SCOPUS:84895927932

VL - 25

SP - 701

EP - 707

JO - SYNLETT

JF - SYNLETT

SN - 0936-5214

IS - 5

M1 - ST-2013-D0987-L

ER -

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