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Continuous heterogeneous catalytic oxidation of primary and secondary alcohols in scCO(2)

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Continuous heterogeneous catalytic oxidation of primary and secondary alcohols in scCO(2). / Chapman, Adrian O.; Akien, Geoffrey R.; Arrowsmith, Nicholas J. et al.
In: Green Chemistry, Vol. 12, No. 2, 2010, p. 310-315.

Research output: Contribution to Journal/Magazine › Journal article › peer-review

Harvard

Chapman, AO, Akien, GR, Arrowsmith, NJ, Licence, P & Poliakoff, M 2010, 'Continuous heterogeneous catalytic oxidation of primary and secondary alcohols in scCO(2)', Green Chemistry, vol. 12, no. 2, pp. 310-315. https://doi.org/10.1039/b913434d

APA

Chapman, A. O., Akien, G. R., Arrowsmith, N. J., Licence, P., & Poliakoff, M. (2010). Continuous heterogeneous catalytic oxidation of primary and secondary alcohols in scCO(2). Green Chemistry, 12(2), 310-315. https://doi.org/10.1039/b913434d

Vancouver

Chapman AO, Akien GR, Arrowsmith NJ, Licence P, Poliakoff M. Continuous heterogeneous catalytic oxidation of primary and secondary alcohols in scCO(2). Green Chemistry. 2010;12(2):310-315. doi: 10.1039/b913434d

Author

Chapman, Adrian O. ; Akien, Geoffrey R. ; Arrowsmith, Nicholas J. et al. / Continuous heterogeneous catalytic oxidation of primary and secondary alcohols in scCO(2). In: Green Chemistry. 2010 ; Vol. 12, No. 2. pp. 310-315.

Bibtex

@article{9a10301493f4426a82a2a43090540815,
title = "Continuous heterogeneous catalytic oxidation of primary and secondary alcohols in scCO(2)",
abstract = "A miniature catalytic reactor has been developed for the oxidation of alcohols with O-2 in supercritical CO2. Particular attention has been given to ensuring good mixing of O-2 and CO2 prior to contact with the substrate. The reactor was optimised using the oxidation of 2-octanol over 5% Pt + 1% Bi on Al2O3 and the mass balance was measured. The reactor was then evaluated for the oxidation of a series of secondary alcohols, and also the primary alcohol, 1-octanol.",
keywords = "SUPERCRITICAL CARBON-DIOXIDE, SELECTIVE OXIDATION, METAL-CATALYSTS, ALDEHYDES, KETONES, CO2",
author = "Chapman, {Adrian O.} and Akien, {Geoffrey R.} and Arrowsmith, {Nicholas J.} and Peter Licence and Martyn Poliakoff",
year = "2010",
doi = "10.1039/b913434d",
language = "English",
volume = "12",
pages = "310--315",
journal = "Green Chemistry",
issn = "1463-9262",
publisher = "Royal Society of Chemistry",
number = "2",

}

RIS

TY - JOUR

T1 - Continuous heterogeneous catalytic oxidation of primary and secondary alcohols in scCO(2)

AU - Chapman, Adrian O.

AU - Akien, Geoffrey R.

AU - Arrowsmith, Nicholas J.

AU - Licence, Peter

AU - Poliakoff, Martyn

PY - 2010

Y1 - 2010

N2 - A miniature catalytic reactor has been developed for the oxidation of alcohols with O-2 in supercritical CO2. Particular attention has been given to ensuring good mixing of O-2 and CO2 prior to contact with the substrate. The reactor was optimised using the oxidation of 2-octanol over 5% Pt + 1% Bi on Al2O3 and the mass balance was measured. The reactor was then evaluated for the oxidation of a series of secondary alcohols, and also the primary alcohol, 1-octanol.

AB - A miniature catalytic reactor has been developed for the oxidation of alcohols with O-2 in supercritical CO2. Particular attention has been given to ensuring good mixing of O-2 and CO2 prior to contact with the substrate. The reactor was optimised using the oxidation of 2-octanol over 5% Pt + 1% Bi on Al2O3 and the mass balance was measured. The reactor was then evaluated for the oxidation of a series of secondary alcohols, and also the primary alcohol, 1-octanol.

KW - SUPERCRITICAL CARBON-DIOXIDE

KW - SELECTIVE OXIDATION

KW - METAL-CATALYSTS

KW - ALDEHYDES

KW - KETONES

KW - CO2

U2 - 10.1039/b913434d

DO - 10.1039/b913434d

M3 - Journal article

VL - 12

SP - 310

EP - 315

JO - Green Chemistry

JF - Green Chemistry

SN - 1463-9262

IS - 2

ER -