Research output: Contribution to Journal/Magazine › Journal article › peer-review
Research output: Contribution to Journal/Magazine › Journal article › peer-review
}
TY - JOUR
T1 - Continuous heterogeneous catalytic oxidation of primary and secondary alcohols in scCO(2)
AU - Chapman, Adrian O.
AU - Akien, Geoffrey R.
AU - Arrowsmith, Nicholas J.
AU - Licence, Peter
AU - Poliakoff, Martyn
PY - 2010
Y1 - 2010
N2 - A miniature catalytic reactor has been developed for the oxidation of alcohols with O-2 in supercritical CO2. Particular attention has been given to ensuring good mixing of O-2 and CO2 prior to contact with the substrate. The reactor was optimised using the oxidation of 2-octanol over 5% Pt + 1% Bi on Al2O3 and the mass balance was measured. The reactor was then evaluated for the oxidation of a series of secondary alcohols, and also the primary alcohol, 1-octanol.
AB - A miniature catalytic reactor has been developed for the oxidation of alcohols with O-2 in supercritical CO2. Particular attention has been given to ensuring good mixing of O-2 and CO2 prior to contact with the substrate. The reactor was optimised using the oxidation of 2-octanol over 5% Pt + 1% Bi on Al2O3 and the mass balance was measured. The reactor was then evaluated for the oxidation of a series of secondary alcohols, and also the primary alcohol, 1-octanol.
KW - SUPERCRITICAL CARBON-DIOXIDE
KW - SELECTIVE OXIDATION
KW - METAL-CATALYSTS
KW - ALDEHYDES
KW - KETONES
KW - CO2
U2 - 10.1039/b913434d
DO - 10.1039/b913434d
M3 - Journal article
VL - 12
SP - 310
EP - 315
JO - Green Chemistry
JF - Green Chemistry
SN - 1463-9262
IS - 2
ER -